ChemicalBook Product Catalog Organic Chemistry Heterocyclic Compounds (S)-(+)-2-(AMINOMETHYL)PYRROLIDINE

(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE

(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE Basic information
Product Name:(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE
Synonyms:(S) 2-AMINOMETHYLPYRROLIDINE;(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE;(S)-(+)-2-(Aminomethyl)pyrrolidine,98%;(S)-(+)-(Aminomethyl)pyrrolidine;(2S)-PYRROLIDIN-2-YL-METHYLAMINE;(S)-pyrrolidin-2-ylMethanaMine;(2S)-2-Pyrrolidinemethanamine;(S)-2-Pyrrolidinemethanamine
CAS:69500-64-7
MF:C5H12N2
MW:100.16
EINECS:
Product Categories:Chiral Compound;Chiral Building Blocks;Heterocyclic Building Blocks;Pyrrolidines
Mol File:69500-64-7.mol
(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE Structure
(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE Chemical Properties
Boiling point 65 °C11 mm Hg(lit.)
density 0.933 g/mL at 25 °C(lit.)
refractive index n20/D 1.482(lit.)
Fp 117 °F
pka10.68±0.10(Predicted)
optical activity[α]20/D +20°, c = 1 in chloroform
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 16-26-36
RIDADR UN 2734 8/PG 2
WGK Germany 3
HazardClass 8/3
PackingGroup II
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE Usage And Synthesis
Chemical PropertiesClear colorless liquid
Uses(S)-(+)-2-(Aminomethyl)pyrrolidine can be used as an organocatalyst:
  • For the asymmetric transformation of (S)-alanine.
  • In the asymmetric α-fluorination of linear and branched aldehydes using N-fluorobenzenesulfonamide as the fluorinating agent.

It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.
DefinitionChEBI: (S)-pyrrolidin-2-ylmethylamine is a pyrrolidin-2-ylmethylamine. It is an enantiomer of a (R)-pyrrolidin-2-ylmethylamine.
General Description(S)-(+)-2-(Aminomethyl)pyrrolidine is a chiral vicinal diamine.
(S)-(+)-2-(AMINOMETHYL)PYRROLIDINE Preparation Products And Raw materials
Z-PRO-PHE-OH (R)-3-(Boc-aminomethyl)pyrrolidine hydrochloride (S)-2-N-CBZ-AMINOMETHYL-PYRROLIDINE HCL (S)-(+)-2-(2,6-XYLIDINOMETHYL)PYRROLIDINE H-GLY-PRO-PRO-OH Z-PRO-D-LEU-OH Z-PRO-ALA-OH H-PRO-GLY-OH H-GLY-PRO-HYP-OH (S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine N-CARBOBENZOXY-L-PROPYL-L-SERINE Z-PHE-PRO-NH2 Z-PRO-NH2 Z-PRO-ILE-OH N-Acetyl-L-prolinamide PPACK, DIHYDROCHLORIDE Z-PRO-PHE-NH2 2-Pyrrolidinecarboxamide,(S)-
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