DIMETHYLCYANAMIDE

DIMETHYLCYANAMIDE Basic information
Product Name:DIMETHYLCYANAMIDE
Synonyms:Dimethylkyanamid;n-cyanodimethylamine;N-Cyano-N-methylmethanamine;DIMETHYLCYANAMIDE;Dimethylcarbaminonitryl;Dimethylcyanamide, 97+%;Cyanodimethylamine;Dimethylamino cyanide
CAS:1467-79-4
MF:C3H6N2
MW:70.09
EINECS:215-991-7
Product Categories:
Mol File:1467-79-4.mol
DIMETHYLCYANAMIDE Structure
DIMETHYLCYANAMIDE Chemical Properties
Melting point -41 °C
Boiling point 161-163 °C(lit.)
density 0.867 g/mL at 25 °C(lit.)
refractive index n20/D 1.41(lit.)
Fp 137 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Hexane (Slightly)
form Liquid
pka-4.76±0.70(Predicted)
color Clear colorless to yellow
EPA Substance Registry SystemDimethylcyanamide (1467-79-4)
Safety Information
Hazard Codes T,F
Risk Statements 23/25
Safety Statements 36/37/39-45
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
RTECS GS6475000
HazardClass 3.2
PackingGroup III
HS Code 29269095
Hazardous Substances Data1467-79-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
DIMETHYLCYANAMIDE Usage And Synthesis
Chemical PropertiesCLEAR COLORLESS TO YELLOWISH LIQUID
UsesDimethylcyanamide in the presence of tetrachlorosilane and zinc chloride is used as a promoter for one-pot, three component synthesis of a novel series of 1,3-oxazines. Being a dialkylcyanamide, it has been proved to be a more reactive substrate toward metal-mediated nucleophilic addition than alkylcyanides.
Production MethodsDimethyl cyanamide is made by the reaction of nitromethane with tris(dimethylamino) arsine.
General DescriptionClear liquid.
Air & Water ReactionsReacts with water to form cyanide gas
Reactivity ProfileNitriles, such as DIMETHYLCYANAMIDE, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids. DIMETHYLCYANAMIDE reacts with oxidizers, water, or steam.
Health HazardACUTE/CHRONIC HAZARDS: DIMETHYLCYANAMIDE is an irritant. It reacts with water to produce toxic and flammable vapors.
Fire HazardDIMETHYLCYANAMIDE is combustible.
Safety ProfilePoison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by inhalation. Flammable when exposed to heat, flame, or oxidzers. Can react with oxidzing materials. To fight fire, use foam, CO2, or dry chemical. When heated to decomposition or in reaction with water or steam it produces toxic fumes of NOx, and CNand flammable vapors. See also CYANIDE
DIMETHYLCYANAMIDE Preparation Products And Raw materials
Preparation Products1,1-DIMETHYLUREA-->N,N,O-TRIMETHYLISOUREA-->N,N’-S-Trimethylisothiouronium Iodide
N-CYANO-3-(IODOMETHYL)-4-(1H,1H-NONAFLUOROPENTYL)PYRROLIDINE 1-Cyanopyrrolidine 4-MORPHOLINECARBONITRILE [(6-CHLOROPYRIDAZIN-3-YL)(METHYL)AMINO]METHANENITRILE N,N-BIS(2-CHLOROBENZYL)CYANAMIDE Cyanamide,(3-aminophenyl)methyl- N,N-BIS(3-CHLOROBENZYL)CYANAMIDE DIBENZYLCYANAMIDE 5-Cyano-5H-dibenz[b,f]azepine DIBUTYLCYANAMIDE N-Cyano-N-[2-(5-methylimidazole-4-methylthio)ethyl]-S-methyl isothiourea (CYANO-METHYL-AMINO)-ACETIC ACID ETHYL ESTER 4-METHYL-PIPERAZINE-1-CARBONITRILE 6-CYANO-1-PROPYL-6-NORFESTUCLAVINE N-CYANO-3-(IODOMETHYL)-4-(1H,1H-PERFLUOROHEPTYL)PYRROLIDINE DIALLYL CYANAMIDE N,N-BIS(4-CHLOROBENZYL)CYANAMIDE METHYL (THIOPHEN-2-YL) CYANOCARBONIMIDODITHIOATE

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