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| | CHLOROTRIS(TRIMETHYLSILYL)SILANE Basic information |
| Product Name: | CHLOROTRIS(TRIMETHYLSILYL)SILANE | | Synonyms: | CHLOROTRIS(TRIMETHYLSILYL)SILANE;1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane;Tris(trimethylsilyl)silyl Chloride;Chlorotris(trimethylsilyl)silane 97%;Tris(Trimethylsilyl) Chlorosilane;Chlorotris(trimethylsilyl)silane solution
;Chlorotris(trimethylsilyl)silane >;Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | | CAS: | 5565-32-2 | | MF: | C9H27ClSi4 | | MW: | 283.11 | | EINECS: | | | Product Categories: | Protecting and Derivatizing Reagents;Protection and Derivatization;Silicon-Based | | Mol File: | 5565-32-2.mol |  |
| | CHLOROTRIS(TRIMETHYLSILYL)SILANE Chemical Properties |
| Melting point | 50-52 °C (lit.) | | Boiling point | 93°C/1.8mmHg(lit.) | | density | 0.877 g/mL at 25 °C | | Fp | 87 °F | | form | powder to lump | | color | White to Almost white | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| | CHLOROTRIS(TRIMETHYLSILYL)SILANE Usage And Synthesis |
| Uses | Super Silyl Protecting Groups
Used for:
- Insertion into a P-P bond
- Diastereoselective aldol and cascade reactions
- Preparation of hypersilyl substituted monophosphines and diphosphines
| | General Description | Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials. |
| | CHLOROTRIS(TRIMETHYLSILYL)SILANE Preparation Products And Raw materials |
| Raw materials | Lithium, [2,2,2-trimethyl-1,1-bis(trimethylsilyl)disilanyl]--->Trisilane, 2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)--->TETRAKIS(TRIMETHYLSILYL)SILANE-->2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)--->N-PHENYLACRYLAMIDE-->TRIS(TRIMETHYLSILYL)SILANE-->Dimethylsulfamoyl chloride-->4-Fluorobenzenesulfonyl chloride-->Methyltrichlorosilane-->Dichlorodimethylsilane-->ZINC | | Preparation Products | Benzene, [(2-methyl-2-propen-1-yl)sulfonyl]- |
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