Cinnamyl chloride

Cinnamyl chloride Basic information

Product Name:	Cinnamyl chloride
Synonyms:	beta-chloromethylstyrene;Propene, 3-chloro-1-phenyl-;r-Chloropropenylbenzene;β-Chloromethylstylene;Cinnamyl chloride;3-PHENYLALLYL CHLORIDE;3-PHENYL-2-PROPENYL CHLORIDE;(3-CHLOROPROPENYL)BENZENE
CAS:	2687-12-9
MF:	C9H9Cl
MW:	152.62
EINECS:	220-246-4
Product Categories:	Pharmaceutical Intermediates
Mol File:	2687-12-9.mol

Cinnamyl chloride Chemical Properties

Melting point	-19 °C (lit.)
Boiling point	108 °C/12 mmHg (lit.)
density	1.096 g/mL at 25 °C (lit.)
vapor pressure	2Pa at 20℃
refractive index	n20/D 1.584(lit.)
Fp	175 °F
storage temp.	2-8°C
form	Liquid
color	Yellow to yellow-brown
Water Solubility	0.2 g/L (20 ºC)
Sensitive	Lachrymatory
BRN	741974
LogP	3.3
CAS DataBase Reference	2687-12-9(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, (3-chloro-1-propenyl)-(2687-12-9)
EPA Substance Registry System	Benzene, (3-chloro-1-propenyl)- (2687-12-9)

Safety Information

Hazard Codes	T+,C
Risk Statements	22-26-34-43-36
Safety Statements	26-28-36/37/39-45-28A-23-27
RIDADR	UN 1760 8/PG 2
WGK Germany	3
RTECS	CZ0919905
Hazard Note	Corrosive/Lachrymatory
TSCA	Yes
HazardClass	8
PackingGroup	III
HS Code	29039990
Toxicity	rat,LC50,inhalation,29mg/m3/4H (29mg/m3),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION,Toksikologicheskii Vestnik. Vol. (4), Pg. 30, 1997.

MSDS Information

Provider	Language
Cinnamyl chloride	English
ACROS	English
SigmaAldrich	English
ALFA	English

Cinnamyl chloride Usage And Synthesis

Chemical Properties	yellow to yellow-brown liquid
Uses	Cinnamyl chloride is used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.
General Description	Cinnamyl chloride reacts regioselectively with aryl and alkenylgold(I) phosphanes in the presence of palladium catalyst in THF to afford the α-substitution product?.

Cinnamyl chloride Preparation Products And Raw materials

Raw materials	Calcium chloride-->Styrene-->4-PHENYL-1,3-DIOXANE-->Methyl cinnamate-->Benzaldehyde-->3-Phenylpropene-3-ol-->3-CHLORO-1-PHENYL-1-PROPANOL-->1,2-Ethanediyl, 1-phenyl- (9CI)-->cis-1,4-Dichloro-2-butene-->Cinnamyl bromide-->Cinnamic acid-->Cinnamyl alcohol
Preparation Products	Stugeron-->Cyclopropanemethanol, 2,2-dichloro-3-phenyl--->(3-methoxy-1-propenyl)benzene-->DIPHENYLCYCLOPROPENONE-->4-Penten-2-one, 5-phenyl--->1H-Indole-2,3-dione, 1-(3-phenyl-2-propen-1-yl)-

Methylene Chloride Chlorodimethylphenylsilane Cassia Aurantium P.E Catechins 8% HPLC Cinnamaldehyde DIPHENYLCYCLOPROPENONE Phenylacetone 1-Chlorohexadecane 1,3-Dichloropropene Acrylamide PHENYL VALERATE Benzene Ammonium chloride 2-Chloroacrylic acid CHLOROPHENYLSILANE 97 Triphenylmethyl Chloride Propiophenone Allylbenzene 2-[[(2-ethylphenyl)(2-hydroxyethyl)amino]methyl]-3,3-difluoro-Propanenitrile

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