Naphthol AS-D

Naphthol AS-D Basic information
Product Name:Naphthol AS-D
Synonyms:1-(2',3'-Hydroxynaphthoylamino)-2-methylbenzene;2-Naphtho-o-toluidide, 3-hydroxy-;3-hydroxy-n-(2-methylphenyl)-2-naphthalenecarboxamid;Acco Naf-Sol AS-D;Acco Naphthol AS-D;Acna Naphthol E;AcnaNaphtholE;Amanil Naphthol AS-D
CAS:135-61-5
MF:C18H15NO2
MW:277.32
EINECS:205-205-0
Product Categories:Substrates;Intermediates of Dyes and Pigments
Mol File:135-61-5.mol
Naphthol AS-D Structure
Naphthol AS-D Chemical Properties
Melting point 196-198 °C
Boiling point 399.7±35.0 °C(Predicted)
density 1.277±0.06 g/cm3(Predicted)
pka8.73±0.40(Predicted)
Colour Index 37520
form powder to crystal
color White to Gray to Brown
NIST Chemistry Reference2-Naphthalenecarboxamide, 3-hydroxy-n-(2-methylphenyl)-(135-61-5)
EPA Substance Registry System2-Naphthalenecarboxamide, 3-hydroxy-N-(2-methylphenyl)- (135-61-5)
Safety Information
Hazard Codes N
Risk Statements 50/53
Safety Statements 60-61
RIDADR UN 3077 9/PG 3
WGK Germany 2
HS Code 2924.29.7790
HazardClass 9
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
Naphthol AS-D Usage And Synthesis
PreparationO-Methylaniline and 3-Hydroxy-2-naphthoic acid condensation.
Flammability and ExplosibilityNonflammable
Properties and Applicationsyellowish powder, melting point for 195 ~ 196 ℃. Insoluble in water solution and sodium carbonate, soluble in naphtha. In sodium hydroxide solution for yellow. Sensitive to air. Mainly used for cotton yarns, cotton fabric, PVA, viscose, silk and vinegar fiber dyeing, also can be used for direct printing, the cotton print and dye discharge printing, and can be used as a quick pigment and organic pigments intermediate. The affinity of cotton is low, medium coupled ability.
Purification MethodsPurify it by recrystallisation from xylene. This gives yellow-green fluorescent solutions at pH 8.2-9.5. [IR: Schnopper et al. Anal Chem 31 1542 1959.] The naphthol AS-D acetate is obtained with AcCl, m 168-169o, and with chloroacetyl chloride naphthol AS-D-chloroacetate is obtained [Moloney et al. J Histochem Cytochem 8 200 1960, Burstone Arch Pathology 63 164 1957]. [Beilstein 12 H 505.]
NAPHTHOL AS-MX PHOSPHATE NAPHTHOL AS-D PHOSPHATE NAPHTHOL AS-GR PHOSPHATE DISODIUM NAPHTHOL AS-TR PHOSPHATE N-(2-ETHYLPHENYL)-3-HYDROXY-2-NAPHTHALENECARBOXAMIDE 2-[2-HYDROXY-3-(2,4-XYLYLCARBAMOYL)-1-NAPHTHYLAZO]PHENOL NAPHTHOL AS-TR ACETATE NAPHTHOL AS-GR PURIFIED GRADE NAPHTHOL AS-D ACETATE (S)-(-)-3,3-Dibromo-1,1-bi-2-naphtol NAPHTHOL AS-KB ACETATE NAPHTHOL AS-MX (R)-(+)-3,3-Dibromo-1,1-bi-2-naphtol NAPHTHOL AS-KB PHOSPHATE NAPHTHOL AS-MX ACETATE Naphthol AS-D NAPHTHOL AS-D CHLOROACETATE NAPHTHOL AS-GR PHOSPHATE

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