ChemicalBook Product Catalog Organic Chemistry Phosphines Bis(triphenylphosphine)iminium chloride

Bis(triphenylphosphine)iminium chloride

Bis(triphenylphosphine)iminium chloride Basic information
Product Name:Bis(triphenylphosphine)iminium chloride
Synonyms:HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE;BIS(TRIPHENYLPHOSPHORANYLIDENE)AMMONIUM CHLORIDE;BIS(TRIPHENYLPHOSPHINE)IMINIUM CHLORIDE;BIS(TRIPHENYLPHOSPHINE)IMINIUMHLORIDE;PPNCI;PHOSPHORUS(1+), TRIPHENYL(P,P,P-TRIPHENYLPHOSPHINEIMIDATO-KN)-, CHLORIDE, (T-4)-;bis((triphenyl-$l^{5}-phosphanylidene)azanium) dichloride;triphenyl-(triphenylphosphoranylideneamino)phosphonium chloride
CAS:21050-13-5
MF:C36H30ClNP2
MW:574.04
EINECS:244-170-6
Product Categories:Furans ,Coumarins;organophosphine ligand;Pharmaceutical Intermediates
Mol File:21050-13-5.mol
Bis(triphenylphosphine)iminium chloride Structure
Bis(triphenylphosphine)iminium chloride Chemical Properties
Melting point 270-272 °C(lit.)
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder
color white
Water Solubility Moderately soluble in water.
BRN 4097979
CAS DataBase Reference21050-13-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20
Safety Statements 26-36-38-36/37/39-22
WGK Germany 3
F 10
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Bis(triphenylphosphine)iminium chloride Usage And Synthesis
Usessuzuki reaction
UsesCo-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.
UsesBis(triphenylphosphoranylidene)ammonium chloride was used in two-phase titration and electrochemistry, done for physiochemical characterization of sildenafil. It was also used in cyclic voltammetry reactions, used to study ion transfer (IT) and electron transfer (ET), at a liquid-liquid interface supported on a metallic electrode.
General DescriptionVisit our Sensor Applications portal to learn more.
Methylene Chloride Diphenylphosphine Tris(triphenylphosphine)rhodiu METHYLPHENYLCHLOROPHOSPHINE Tetrakis(triphenylphosphine)platinum Calcium chloride Sodium chloride Zinc chloride Choline chloride Chlorodiphenylphosphine Ammonium chloride Oxalyl chloride Triphenylphosphine oxide Triphenylphosphine Potassium chloride Thionyl chloride Bis(triphenylphosphine)iminium chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile
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