DI-O-TOLYLCHLOROPHOSPHINE

DI-O-TOLYLCHLOROPHOSPHINE Basic information
Product Name:DI-O-TOLYLCHLOROPHOSPHINE
Synonyms:Bis(2-methylphenyl)phosphinous chloride, Chlorobis(2-methylphenyl)phosphine;Di-o-tolylchlorophosphine, min. 98%;Chlorobis(o-tolyl)phosphine;Di(o-methylphenyl)phosphine chloride;BIS(O-TOLYL)CHLOROPHOSPHINE;BIS(2-METHYLPHENYL)PHOSPHINOUS CHLORIDE;DI(2-TOLYL)CHLOROPHOSPHINE;DI-O-TOLYLCHLOROPHOSPHINE
CAS:36042-94-1
MF:C14H14ClP
MW:248.69
EINECS:
Product Categories:organophosphine halide
Mol File:36042-94-1.mol
DI-O-TOLYLCHLOROPHOSPHINE Structure
DI-O-TOLYLCHLOROPHOSPHINE Chemical Properties
Melting point 57°C
Boiling point 174-178°C/3mm
Fp 174-178°C/3mm
storage temp. 2-8°C
form liquid
color white to yellow
Water Solubility Not miscible or difficult to mix in water.
Sensitive Moisture Sensitive
Safety Information
Hazard Codes F,C
Risk Statements 17-34
Safety Statements 26-36/37/39-45
RIDADR UN 2845 4.2/PG 1
WGK Germany 3
10-21
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
DI-O-TOLYLCHLOROPHOSPHINE Usage And Synthesis
UsesChlorodi(o-tolyl)phosphine is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.
Purification MethodsIt is purified by fractional distillation in a vacuum (b 179-183o/7mm, 253-257o/15mm,) and the distillate solidifies (m 36o, also reported is m 37o). [Weinberg J Org chem. 40 3586 1975, McEwen et al. J Am Chem Soc 100 7304 1978, Beilstein 16 H 769, 16 IV 970 for chlorodi(p-tolyl)phosphine.]
DI-O-TOLYLCHLOROPHOSPHINE Preparation Products And Raw materials
Preparation ProductsBIS(O-TOLYL)PHOSPHINE
METHYLPHENYLCHLOROPHOSPHINE DI-P-TOLYLPHOSPHINE BIS(O-TOLYL)PHOSPHINE Chlorodiphenylphosphine METHYLPHENYLPHOSPHINIC CHLORIDE DI-O-TOLYLCHLOROPHOSPHINE

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