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| | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Basic information | | Application Reaction |
| Product Name: | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) | | Synonyms: | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II), 98%;Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladiuM(II),98%;Cinnamylpalladium chloride dimer;PalladiuM(II)(pi-cinnaMyl) Chloride DiMer;PalladiuM(II)(π-cinnaMyl) Chloride DiMer;PalladiuM(pi-cinnaMyl) chloride diMer 97%;Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(Ⅱ);Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium | | CAS: | 12131-44-1 | | MF: | C18H12Cl2Pd2 | | MW: | 512.03 | | EINECS: | 234-579-8 | | Product Categories: | Pd | | Mol File: | 12131-44-1.mol | ![Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Structure](CAS/20211123/GIF/12131-44-1.gif) |
| | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Chemical Properties |
| Melting point | 218-220°C | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | crystal | | color | yellow | | Sensitive | air sensitive |
| Hazard Codes | T | | Risk Statements | 23-43 | | Safety Statements | 36/37-45 | | RIDADR | UN 2811 6.1 / PGIII | | WGK Germany | 3 | | HS Code | 2843909000 |
| | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Usage And Synthesis |
| Application | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(ii) is an important organic regant for the use of transition-metal-mediated organic syntheses. It can be used as a catalyst for the ammonia cross-coupling reactions to synthesize arylamines and conversion of aryl triflates to fluorides.
| | Reaction |
- Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
- Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.
- Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.
- Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .
| | Uses | Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
- Ammonia cross-coupling reactions to synthesize arylamines.
- Conversion of aryl triflates to fluorides.
It can also be used as a source of palladium in the asymmetric α-arylation of amides. |
| | Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Preparation Products And Raw materials |
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