VINYLBENZYL ALCOHOL

VINYLBENZYL ALCOHOL Basic information
Product Name:VINYLBENZYL ALCOHOL
Synonyms:AURORA KA-7349;ALPHA-VINYLBENZYL ALCOHOL;VINYLBENZYL ALCOHOL;alpha-Vinylbenzyl alcohol 97%;Fluoxetine intermediate FXT-2a;VINYLBENZYL ALCOHOL ISO 9001:2015 REACH;α-Vinylbenzyl alcohol
CAS:42273-76-7
MF:C9H10O
MW:134.18
EINECS:
Product Categories:Acyclic;Alkenes;Organic Building Blocks
Mol File:42273-76-7.mol
VINYLBENZYL ALCOHOL Structure
VINYLBENZYL ALCOHOL Chemical Properties
Boiling point 101-102 °C/12 mmHg (lit.)
density 1.021 g/mL at 25 °C (lit.)
refractive index n20/D 1.54(lit.)
Fp 202 °F
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
VINYLBENZYL ALCOHOL Usage And Synthesis
Usesα-Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols.
Usesα?Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols.
Synthesis Reference(s)The Journal of Organic Chemistry, 52, p. 3524, 1987 DOI: 10.1021/jo00392a006
General Descriptionα-Vinylbenzyl alcohol is an allyl alcohol derivative. Its isomerization reaction using a novel ternary catalyst system has been reported. The kinetic resolution of racemic α-vinylbenzyl alcohol by tungsten-catalyzed asymmetric epoxidation method has been repoorted. The coupling reaction of α-vinylbenzyl alcohol and aldehydes in the presence of RuCl2(PPh3)3 catalyst and In(OAc)3 as a co-catalyst in ionic liquids has been investigated. Etherification reaction of glycerol with α-vinylbenzyl alcohol in the presence of sulfonic catalyst immobilized on silica (SiO2–SO3H) has been reported.
VINYLBENZYL ALCOHOL Preparation Products And Raw materials
3-[1-NITRO-2-(4-PHENOXYANILINO)VINYL]-2-BENZOFURAN-1(3H)-ONE 3-(1-NITRO-2-[3-(TRIFLUOROMETHYL)ANILINO]VINYL)-2-BENZOFURAN-1(3H)-ONE 3-[2-(DIMETHYLAMINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE 3-[2-(4-CHLOROANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE 3-[2-(5-CHLORO-2-HYDROXYANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE 1,2,3-TRIPHENYL-1-INDENOL 3-[2-(3-CHLOROANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE INDENONE ETHYLENE KETAL 2-METHYL-1-PHENYL-2-PROPEN-1-OL 3-[2-(2,4-DIMETHYLANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE 3-[2-(4-FLUOROANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE VINYLBENZYL ALCOHOL 3-[2-(3,5-DICHLOROANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE 3-(1-NITRO-2-[4-(TRIFLUOROMETHOXY)ANILINO]VINYL)-2-BENZOFURAN-1(3H)-ONE 3-[2-(2,4-DIFLUOROANILINO)-1-NITROVINYL]-2-BENZOFURAN-1(3H)-ONE 4-([2-NITRO-2-(3-OXO-1,3-DIHYDRO-2-BENZOFURAN-1-YL)VINYL]AMINO)BENZENECARBOXYLIC ACID 2',4'-DIHYDROXY-3'-PRENYLCHALCONE 3-(2-ANILINO-1-NITROVINYL)-2-BENZOFURAN-1(3H)-ONE

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