2-Ethoxynaphthalene

2-Ethoxynaphthalene Basic information
Product Name:2-Ethoxynaphthalene
Synonyms:nerolinnew;2-ETHOXYNAPHTHALENE;AKOS 92213;NEROLIN;NEROLIN BROMELIA;NEROLINE;Naphthalene, 2-ethoxy-;BETA-NAPHTHYL ETHYL ETHER
CAS:93-18-5
MF:C12H12O
MW:172.22
EINECS:202-226-7
Product Categories:Naphthalene derivatives;Aromatic Esters
Mol File:93-18-5.mol
2-Ethoxynaphthalene Structure
2-Ethoxynaphthalene Chemical Properties
Melting point 35-37 °C(lit.)
Boiling point 282°C
density 1.0640
vapor pressure 0.518Pa at 25℃
refractive index 1.5975 (estimate)
FEMA 2768 | BETA-NAPHTHYL ETHYL ETHER
Fp 134°C
solubility alcohol: soluble
form neat
color White to Almost white
Odorat 10.00 % in dipropylene glycol. naphtha floral orange blossom powdery grape
Odor Typenaphthyl
Water Solubility insoluble
Merck 14,3752
JECFA Number1258
BRN 2042397
LogP3.747 at 25℃
CAS DataBase Reference93-18-5(CAS DataBase Reference)
NIST Chemistry ReferenceNaphthalene, 2-ethoxy-(93-18-5)
EPA Substance Registry SystemNaphthalene, 2-ethoxy- (93-18-5)
Safety Information
Hazard Codes Xi
Risk Statements 38
Safety Statements 26-36-24/25
WGK Germany 2
RTECS QJ6900000
TSCA Yes
HS Code 29093090
MSDS Information
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2-Ethoxynaphthalene English
SigmaAldrich English
ACROS English
ALFA English
2-Ethoxynaphthalene Usage And Synthesis
Description(β-Naphthyl ethyl ether has an odor suggestive of orange blossom with a faint, fruity undertone. It has a corresponding sweet taste suggestive of strawberry (on extreme dilution only). This substance may be prepared by esterification of P-naphthol with ethyl alcohol and sulfuric acid; from β-naphtholsodium and diethylsulfate in weak aqueous base; fromβ-naphtholsodium and ethyl bromide.
Chemical Propertiesβ-Naphthyl ethyl ether has an odor suggestive of orange blossom with a faint, fruity undertone. Also, it has a corresponding sweet taste suggestive of strawberry (on extreme dilution only)
Chemical PropertiesEthyl 2-Naphthyl Ether forms white crystals (mp 37–38°C), with a mild, long-lasting, orange blossom fragrance.
Chemical Propertieslight brown crystals
UsesThe fluorescence of 2-Ethoxynaphthalene has been shown to be weakly quenched by m-dimethlphthalate and methyl benzoate. Importantly, at increased concentration methyl benzoate enhances the fluorescence by increasing the polarity of the solvent .
PreparationBy esterification of β-naphthol with ethyl alcohol and sulfuric acid; from β-naphtholsodium and diethylsulfate in weak aqueous base; from β-naphtholsodium and ethyl bromide.
DefinitionChEBI: 2-Ethoxynaphthalene is a member of naphthalenes.
Taste threshold valuesTaste characteristics at 4 ppm: powdery, floral, soapy and heavy with a berry and grape nuance.
General DescriptionNerolin bromelia is an alkyl ether of 2-naphthol, which is generally used as a perfume and flavoring compound.
Flammability and ExplosibilityNotclassified
Purification MethodsCrystallise it from pet ether or EtOH (m 37-38o). Dry it in vacuo, or distil it in a vacuum. The picrate has m 104.5o (from EtOH or CHCl3). [Beilstein 6 H 606, 6 II 578, 6 III 2972, 6 IV 4257.]
2-Ethoxynaphthalene Preparation Products And Raw materials
Raw materialsDiethyl sulfate
Preparation Products2-Ethoxynaphthalene-1-carbonyl chloride-->2-ETHOXY-1-NAPHTHOIC ACID-->2-ETHOXY-1-NITRONAPHTHALENE-->1-(2-ethoxynaphthalen-1-yl)ethanone
6-AMINO-2-ETHOXYNAPHTHALENE 4-ethoxynaphthalene-1-sulfonyl chloride 1-ETHOXYNAPHTHALENE 97%,alpha-Ethoxynaphthalene,1-ETHOXYNAPHTHALENE 1-AMINO-2-ETHOXYNAPHTHALENE-6-SULFONIC ACID, SODIUM SALT (2-NAPHTHOXY)ACETIC ACID N-HYDROXYSUCCINIMIDE ESTER C8E3 sodium 5-amino-6-ethoxynaphthalene-2-sulphonate 3-ethoxynaphthalene-2-carboxylic acid 5,7-dibromoquinolin-8-yl 4-ethoxynaphthalene-1-sulfonate 2-Naphthyl-beta-D-galactopyranoside Ethoxyquin CRESYL VIOLET PERCHLORATE DULCITOL Ethyl ethoxyacetate 6-Ethoxynaphthalene-2,3-diol NAPHTHOL AS ACETATE acetic acid, triethoxy-, ethyl ester Meldola's blue

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