3-Methoxyacetophenone

3-Methoxyacetophenone Basic information

Product Name:	3-Methoxyacetophenone
Synonyms:	3-ACETYLANISOLE;1-(3-methoxyphenyl)ethanone;3'-METHOXYACETOPHENONE;3-METHOXYACETOPHENONE;M-ACETYLANISOLE;M-ACETANISOLE;3'-Methoxyacetophenone m-Acetanisole 3-Acetanisole;3-Methoxyacetophenone,>99%
CAS:	586-37-8
MF:	C9H10O2
MW:	150.17
EINECS:	209-573-3
Product Categories:	Aromatic Acetophenones & Derivatives (substituted);bc0001
Mol File:	586-37-8.mol

3-Methoxyacetophenone Chemical Properties

Melting point	-7 °C
Boiling point	239-241 °C(lit.)
density	1.094 g/mL at 25 °C(lit.)
vapor pressure	2.41-10.665Pa at 20-25℃
refractive index	n20/D 1.542(lit.)
Fp	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Chloroform (Slightly), Ethyl Acetate (Slightly)
form	Liquid
Specific Gravity	1.094
color	Clear slightly yellow to slightly brown
Water Solubility	Fully miscible in water. Soluble in alcohol.
Sensitive	Light Sensitive
BRN	878552
LogP	1.86-2.085 at 20-25℃
CAS DataBase Reference	586-37-8(CAS DataBase Reference)
NIST Chemistry Reference	Ethanone, 1-(3-methoxyphenyl)-(586-37-8)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	36/38-22-36/37/38
Safety Statements	23-24/25-37/39-26-36
WGK Germany	3
Hazard Note	Irritant
HS Code	29145000

MSDS Information

Provider	Language
m-Methoxyacetophenone	English
SigmaAldrich	English
ACROS	English
ALFA	English

3-Methoxyacetophenone Usage And Synthesis

Chemical Properties	clear slightly yellow to slightly brown liquid
Uses	It is applied in the asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes.
Synthesis Reference(s)	Journal of the American Chemical Society, 109, p. 7137, 1987 DOI: 10.1021/ja00257a038 Synthesis, p. 406, 1987 DOI: 10.1055/s-1987-27965
Flammability and Explosibility	Nonflammable

3-Methoxyacetophenone Preparation Products And Raw materials

Raw materials	Benzene, 1-methoxy-3-(1-methylethenyl)--->3-Methoxyphenylboronic acid-->3-ETHYNYLANISOLE 96-->3'-METHOXYPHENACYL BROMIDE-->Acetovanillone-->3-Bromoanisole
Preparation Products	2-Phenylbenzoxazole-->2'-Hydroxy-5'-methoxyacetophenone-->2-(3-METHOXYPHENYL)QUINOLINE-4-CARBOXYLIC ACID-->3'-METHOXY-3-(4-METHYLPHENYL)PROPIOPHENONE-->5-(3-METHOXYPHENYL)-5-METHYLIMIDAZOLIDINE-2,4-DIONE-->(2E)-1-(3-methoxyphenyl)-3-(thiophen-2-yl)prop-2-en-1-one-->2-(3-METHOXYPHENYL)-8-METHYLQUINOLINE-4-CARBOXYLIC ACID

3,5-Dibenzyloxyacetophenone 2',6'-Dihydroxy-3'-methyl-4'-methoxyacetophenone,2,6-Dihydroxy-3-methyl-4-methoxyacetophenone 5-Methoxy-3,4-dihydro-2H-naphthalen-1-one 2-Hydroxy-3-iodo-4,6-dimethoxy acetophenone 2-BROMO-2',5'-DIMETHOXYACETOPHENONE 3'-METHOXYPHENACYL BROMIDE Methoxy 2,3,3',4'-TETRAMETHOXYBENZOPHENONE α,α-Bis(p-nitroanilino)-4'-methoxyacetophenone 2-AMINO-4-METHOXYACETOPHENONE, 98+% 5,6-Dimethoxy-1-indanone L-PICEIN 2-Bromoacetophenone 2',4'-Dihydroxy-3',5'-diprenyl-6'-methoxyacetophenone,3',5'-Bis(3-methyl-2-butenyl)-4',6'-dihydroxy-2'-methoxyacetophenone 3-CHLOROMETHYL-4-METHOXYACETOPHENONE 2'-AMINO-4',5'-DIMETHOXYACETOPHENONE 1-METHOXYACETOPHENONE 3',5'-Dimethoxyacetophenone

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