Cyphenothrin

Cyphenothrin Basic information
Product Name:Cyphenothrin
Synonyms:2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicacicyano(3-phe;2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicacicyano(3-phenoxyphenyl)methylester;Cyano-3-Phenoxybenzyl2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate;Cyclopropanecarboxylicacid,2,2-dimethyl-3-(2-methyl-1-propenyl)-,cyano(3-phenoxyphenyl)methylester;CYPHENOTHRIN;D-CYPHENOTHRIN;D-TRANS-CYPHENOTHRIN;CYPHENOTHRIN MIXTURE OF CIS AND TRANS IS
CAS:39515-40-7
MF:C24H25NO3
MW:375.46
EINECS:254-484-5
Product Categories:Alpha sort;C;CAlphabetic;CO - CZPesticides;Insecticides;Pesticides&Metabolites;Pyrethroids
Mol File:39515-40-7.mol
Cyphenothrin Structure
Cyphenothrin Chemical Properties
Melting point 25°C
Boiling point 504.24°C (rough estimate)
density d2525 1.083
vapor pressure 1.2×10-4pa 20°C
refractive index 1.5614 (estimate)
solubility Chloroform, DMSO (Slightly), Methanol (Slightly)
Water Solubility 0.001 mg l-1 (23 °C)
form neat
Merck 13,2797
Stability:Light Sensitive
CAS DataBase Reference39515-40-7(CAS DataBase Reference)
EPA Substance Registry SystemCyphenothrin (39515-40-7)
Safety Information
Hazard Codes Xn;N,N,Xn
Risk Statements 22-50/53
Safety Statements 60-61
RIDADR UN 2810
WGK Germany 3
RTECS GZ1453500
HS Code 29269090
Hazardous Substances Data39515-40-7(Hazardous Substances Data)
Cyphenothrin Usage And Synthesis
Chemical PropertiesThick, yellow liquid.
UsesCyphenothrin controls insects in household, public health and industrial situations. It is also used to control insects which attack wood and fabrics.
UsesInsecticide.
DefinitionChEBI: Cyphenothrin is a cyclopropanecarboxylate ester. It has a role as a pyrethroid ester insecticide and an agrochemical. It is functionally related to a chrysanthemic acid.
Potential ExposurePyrethroid insecticide. Those involved in the manufacture and application of this agricultural chemical.
Metabolic pathwayCyphenothrin is the name given to the α-RS,1RS-cis-trans isomer mixture (racemic). The product now used is cyphenothrin which is 95% 1R and 75% trans. It has no field use because the chrysanthemate moiety is very sensitive to photodegradation. A study in rodents has been reported. Cyphenothrin is degraded mainly by photo-oxidation and by hydrolysis and oxidation in plants and animals.
ShippingUN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required
DegradationCyphenothrin is stable under normal storage conditions but it is labile to base, being hydrolysed to trans-2,2-dimethyl-3-(2-methylprop-1-enyl)- cyclopropanecarboxylic acid (2,trans-chrysanthemic acid) and 3-phenoxybenzaldehyde (3, 3PBAl) and cyanide ion (Scheme 1). It is sensitive to light (see phenothrin for expected products).
IncompatibilitiesMay react violently with strong oxidi- zers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders, or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate
Waste DisposalIncineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Noncombustible con- tainers should be crushed and buried under more than 40 cm of soil .
Cyphenothrin Preparation Products And Raw materials
Empenthrin Cyclopropane rich-d-t-Prallethrin ETHANE Methylene dithiocyanate Allethrin Dimethyl fumarate Fenvalerate Fenpropathrin theta-Cypermethrin rich_d_transallethrin Cyanoacetic acid Cyclopropanecarboxylic acid Ethyl N-cyanoethanimideate Dimethyl ether Cyano Cyphenothrin ETHYL 2-CYANOACRYLATE

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