3-Bromo-4-methoxybenzaldehyde

3-Bromo-4-methoxybenzaldehyde Basic information
Product Name:3-Bromo-4-methoxybenzaldehyde
Synonyms:Benzaldehyde, 3-bromo-4-methoxy-;p-Anisaldehyde, 3-bromo-;AKOS BBS-00003260;AKOS B004285;ASISCHEM N43045;OTAVA-BB BB0125160184;3-BROMO-4-METHOXYBENZALDEHYDE;3-BROMO-P-ANISALDEHYDE
CAS:34841-06-0
MF:C8H7BrO2
MW:215.04
EINECS:252-241-8
Product Categories:Building Blocks;C8;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Benzaldehyde;Adehydes, Acetals & Ketones;Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds;Aromatic Aldehydes & Derivatives (substituted);Aldehydes
Mol File:34841-06-0.mol
3-Bromo-4-methoxybenzaldehyde Structure
3-Bromo-4-methoxybenzaldehyde Chemical Properties
Melting point 51-54 °C (lit.)
Boiling point 108-110°C 1mm
density 1.5313 (rough estimate)
refractive index 1.5500 (estimate)
Fp 108-110°C/1mm
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, DMSO, Ethyl Acetate
form Solid
color Off-White
Sensitive Air Sensitive
BRN 1636939
CAS DataBase Reference34841-06-0(CAS DataBase Reference)
NIST Chemistry Reference3-Bromo-4-methoxybenzaldehyde(34841-06-0)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 36/37/38-22
Safety Statements 37/39-26
WGK Germany 3
HazardClass IRRITANT, AIR SENSITIVE
HS Code 29130000
MSDS Information
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3-Bromo-4-methoxybenzaldehyde Usage And Synthesis
Chemical PropertiesWHITE TO BEIGE SOLID
Uses3-Bromo-4-methoxybenzaldehyde may be used in the following studies:
  • Asymmetric synthesis of a novel β-hydroxy-α-amino acid derivative, via Mukaiyama aldol reaction.
  • Synthesis of 2-(3-bromo-4-methoxyphenyl)-5-fluorobenzothiazole.
  • Preparation of 5-[(Z)-2-(3-bromo-4-methoxyphenyl)vinyl]-1,2-3-trimethoxybenzene.
  • Total synthesis of engelhardione.
  • Starting reagent for the synthesis of (2E)-3-(3-bromo-4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one.
Synthesis Reference(s)Tetrahedron, 41, p. 2903, 1985 DOI: 10.1016/S0040-4020(01)96614-1
General Description3-Bromo-4-methoxybenzaldehyde is formed by the solvent-free bromination of 4-methoxybenzaldehyde using 1,3-di-n-butylimidazolium tribromide, as a brominating reagent.
3-Bromo-4-methoxybenzaldehyde Preparation Products And Raw materials
Preparation Products3-BROMO-4-METHOXYCINNAMIC ACID
7-Bromobenzo[1,3]dioxole-5-carbaldehyde 5-bromo-2-methoxybenzaldehyde [4-anilino-6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazin-2-yl]hydrazone 3-bromo-4-methoxybenzaldehyde (4,6-dianilino-1,3,5-triazin-2-yl)hydrazone 2-(2,6-DIBROMO-4-FORMYLPHENOXY)ACETIC ACID 4-[2-(4-allyl-2-methoxyphenoxy)ethoxy]-3-bromo-5-methoxybenzaldehyde [2,6-di(1-pyrrolidinyl)-4-pyrimidinyl]hydrazone 5-BROMO-2,4-DIMETHOXYBENZALDEHYDE 5-BENZYLOXY-2-BROMO-4-METHOXYBENZALDEHYDE OXIME 5-BROMO-2-METHOXYBENZALDEHYDE N-PHENYLTHIOSEMICARBAZONE 5-BROMOVERATRALDEHYDE METHYL 3-BROMO-4-METHOXYBENZOATE 98 3-BROMO-4,5-DIMETHOXYBENZOIC ACID 3,5-DIBROMO-4-METHOXYBENZOIC ACID 5-bromo-2-methoxybenzaldehyde (5,6-diphenyl-1,2,4-triazin-3-yl)hydrazone 2,5-Dimethoxybenzaldehyde 3,5-DIBROMO-2-HYDROXY-4-METHOXYBENZALDEHYDE ETHYL 2-(2,6-DIBROMO-4-FORMYLPHENOXY)ACETATE 3-bromo-4-methoxybenzaldehyde 2-pyridinylhydrazone 5-BROMO-2-METHOXYBENZALDEHYDE N-(3-CHLOROPHENYL)THIOSEMICARBAZONE

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