ChemicalBook Product Catalog Chemical Reagents Silane reagent DI-TERT-BUTYLSILANE

DI-TERT-BUTYLSILANE

DI-TERT-BUTYLSILANE Basic information
Product Name:DI-TERT-BUTYLSILANE
Synonyms:DI-T-BUTYL SILANE;Ditertiarybutylsilane;Di-tert-butylsilane 97%;bis(1,1-dimethylethyl)-silan;DI-TERT-BUTYLSILANE;Di-tert-Butylsilane>;Silane, bis(1,1-dimethylethyl)-
CAS:30736-07-3
MF:C8H20Si
MW:144.33
EINECS:
Product Categories:Chemical Synthesis;Organometallic Reagents;Si (Classes of Silicon Compounds);Si-H Compounds;Organometallic Reagents;Organosilicon;Others
Mol File:30736-07-3.mol
DI-TERT-BUTYLSILANE Structure
DI-TERT-BUTYLSILANE Chemical Properties
Melting point -38 °C (lit.)
Boiling point 129-130 °C (lit.)
density 0.729 g/mL at 25 °C (lit.)
refractive index n20/D 1.42(lit.)
Fp 28 °F
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.74
Hydrolytic Sensitivity3: reacts with aqueous base
CAS DataBase Reference30736-07-3(CAS DataBase Reference)
EPA Substance Registry SystemSilane, bis(1,1-dimethylethyl)- (30736-07-3)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-33
RIDADR UN 1993 3/PG 1
WGK Germany 3
TSCA No
HS Code 2931.90.9010
HazardClass 3
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
DI-TERT-BUTYLSILANE Usage And Synthesis
UsesDi-tert-butylsilane can be used as a reagent to synthesize:
  • 1,1-di-tert-butyl-N-phenylsilanamine by dehydrogenative coupling with aniline in the presence of supported gold catalyst.
  • Benzyloxy di-tert-butylsilane by dehydrocoupling of benzyl alcohol using NaOH as a catalyst.
  • Di-tert-butyl(3-cyclohexylprop-1-yn-1-yl)silane by silylation reaction with 2-propyn-1-ylcyclohexane using alkali metal hydroxide as a catalyst.

ApplicationSterically-hindered silane reducing agent.
DI-TERT-BUTYLSILANE Preparation Products And Raw materials
SALOR-INT L170445-1EA AKOS 90988 CHLORO-DI-TERT-BUTYLSILANE TRI-T-BUTYLSILANE DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) DI-T-BUTYLMETHYLSILANE DI-TERT-BUTYL-DIETHOXYSILANE DI-TERT-BUTYLDICHLOROSILANE N-BUTYLSILANE di-t-butyldifluorosilane DI-T-BUTYLMETHYLCHLOROSILANE DI-TERT-BUTYLSILANE
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