ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic acids 2-Methoxyphenylacetic acid

2-Methoxyphenylacetic acid

2-Methoxyphenylacetic acid Basic information
Product Name:2-Methoxyphenylacetic acid
Synonyms:Adjacent Methoxy benzene acetic acid;NSC 16257;NSC 110708;2-Methoxyphenylacetic acid, 99% 25GR;2-(Carboxymethyl)anisole;2-Methoxyphenylacetic acid ,99%;2-Methoxyphenylaceti;Ortho methoxy phenyl acetic acid
CAS:93-25-4
MF:C9H10O3
MW:166.17
EINECS:202-231-4
Product Categories:Carboxylic Acids;Aromatics;Miscellaneous Reagents;Aromatic Phenylacetic Acids and Derivatives;Carbonyl Compounds;C9
Mol File:93-25-4.mol
2-Methoxyphenylacetic acid Structure
2-Methoxyphenylacetic acid Chemical Properties
Melting point 122-125 °C (lit.)
Boiling point 254.38°C (rough estimate)
density 1.1708 (rough estimate)
refractive index 1.5101 (estimate)
Fp 117°C (External MSDS)
storage temp. Store below +30°C.
solubility 9.2g/l
form Crystalline Powder
pka4.14±0.10(Predicted)
color White to slightly pink-cream
Water Solubility SOLUBLE
BRN 2047573
LogP1.420 (est)
CAS DataBase Reference93-25-4(CAS DataBase Reference)
NIST Chemistry ReferenceBenzeneacetic acid, 2-methoxy-(93-25-4)
EPA Substance Registry SystemBenzeneacetic acid, 2-methoxy- (93-25-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25
WGK Germany 3
Hazard Note Irritant
TSCA Yes
HS Code 29189090
MSDS Information
ProviderLanguage
2-Methoxyphenylacetic acid English
SigmaAldrich English
ACROS English
ALFA English
2-Methoxyphenylacetic acid Usage And Synthesis
Chemical PropertiesWHITE TO SLIGHTLY PINK-CREAM CRYSTALLINE POWDER
Uses2-Methoxyphenylacetic acid is used as pharmaceutical intermediate.
Synthesis Reference(s)Journal of the American Chemical Society, 70, p. 1930, 1948 DOI: 10.1021/ja01185a084
General DescriptionThe cytotoxic potential of 2-methoxyphenylacetic acid was studied.
Purification MethodsCrystallise the acid from H2O, EtOH or aqueous EtOH, pet ether/Et2O and dry it in a vacuum desiccator over Sicapent. The amide has m 131o (from EtOH). [Beilstein 10 H 188, 10 III 422, 10 IV 536.]
2-Methoxyphenylacetic acid Preparation Products And Raw materials
Preparation Products2-METHOXYPHENYLACETYL CHLORIDE-->1-(2,4-DIHYDROXYPHENYL)-2-(2-METHOXYPHENYL)ETHAN-1-ONE-->2-Methoxybenzyl isocyanate-->(2-Methyl-1H-indol-3-yl)-1-naphthalenylmethanone
2-Methoxybenzoic acid 4-Hydroxy-3-methoxyphenylacetic Acid-d3 4-Hydroxy-3-Methoxyphenylacetic Acid Coumarin 2,3-DIFLUORO-6-METHOXYPHENYLACETIC ACID Amino-4-methoxyben-zeneacetic acid 3-BROMO-4-METHOXYPHENYLACETIC ACID 2-BROMO-4,5-DIMETHOXYPHENYLACETIC ACID Ethyl 2-(Chlorosulfonyl)acetate 2-(DIFLUOROMETHOXY)PHENYLACETIC ACID 4-Ethoxy-3-methoxyphenylacetic acid 3,6-DICHLORO-2-METHOXYPHENYLACETIC ACID Phenethyl phenylacetate 3,5-dimethoxyphenylacetic acid 2-Methylphenylacetic acid 4-(TRIFLUOROMETHOXY)PHENYLACETIC ACID 3-chloro-4-methoxyphenylacetic acid phosphoric acid 2,6-DIFLUORO-4-METHOXYPHENYLACETIC ACID
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