Methyltris(methylisobutylketoxime)silane

Methyltris(methylisobutylketoxime)silane Basic information
Background Background Uses
Product Name:Methyltris(methylisobutylketoxime)silane
Synonyms:methyltris(methylsobutyldetoximo)silane,tech-95;METHYLTRIS(METHYLISOBUTYLKETOXIMINO)SILANE, tech-95;METHYL TRIS (METHYL ISOBUTYL KETOXIME) SILANE;Methyl tris-(methyl isobutyl ketoximino) silane;Methyl tris (MIBKO) silane. Methyl tris-(methyl isobutyl ketoximino) silane;2-Pentanone, 4-methyl-, 2,2',2''-[O,O',O''-(methylsilylidyne)trioxime];Vinyl tris(methylisobutylketoximino) silane;(2E,2'E,2''E)-O,O',O''-(methylsilanetriyl)tris(4-methyl-4-methylpentan-2-one oxime)
CAS:37859-57-7
MF:C19H39N3O3Si
MW:385.62
EINECS:685-131-7
Product Categories:Crosslinkers;Crosslinking Agents;Oximino Silanes
Mol File:37859-57-7.mol
Methyltris(methylisobutylketoxime)silane Structure
Methyltris(methylisobutylketoxime)silane Chemical Properties
Boiling point 403.3±28.0 °C(Predicted)
density 0.92-0.94
refractive index 1.4513
Specific Gravity0.93
Hydrolytic Sensitivity7: reacts slowly with moisture/water
EPA Substance Registry System2-Pentanone, 4-methyl-, 2,2',2''-[O,O',O''-(methylsilylidyne)trioxime] (37859-57-7)
Safety Information
MSDS Information
Methyltris(methylisobutylketoxime)silane Usage And Synthesis
BackgroundThere has been a long felt need in the industry for tetrafunctional oximino silanes which do not require organic solvents or mixing with trifunctional oximino silanes. We have surprisingly discovered that the novel tetrakis oximino silane, e.g. tetrakis-(methyl isobutyl ketoximino) silane is liquid and thus do not suffer with the same problems as their solid counterparts. These new silanes offer the ability to employ solvent-free formulations, if not significantly decrease solvent content in the composition. In addition, there is added flexibility and simplification when formulating room temperature moisture-curable silicone compositions. Because the new silanes are liquid tetrafunctional oximino silanes, one can add more of these silanes to increase the cure rate of the composition. The amount of other tetrafunctional oximino silanes which can be used in this type of silicone composition is limited by their solubility in the solvent.
In addition to the novel liquid tetrafunctional oximino silanes, we have also found that when these novel oximino silanes (tetra-oximino, tris-oximino or bis-oximino) are formulated with hydroxyl terminated polydimethylsiloxane (HTPDMS), an optically clear silicone rubber results.
BackgroundThere has been a long felt need in the industry for tetrafunctional oximino silanes which do not require organic solvents or mixing with trifunctional oximino silanes. As the novel tetrakis oximino silane, e.g. tetrakis-(methyl isobutyl ketoximino) silane is liquid and thus do not suffer with the same problems as their solid counterparts. These new silanes offer the ability to employ solvent-free formulations, if not significantly decrease solvent content in the composition. In addition, there is added flexibility and simplification when formulating room temperature moisture-curable silicone compositions. Because the new silanes are liquid tetrafunctional oximino silanes, one can add more of these silanes to increase the cure rate of the composition. The amount of other tetrafunctional oximino silanes which can be used in this type of silicone composition is limited by their solubility in the solvent.
In addition to the novel liquid tetrafunctional oximino silanes, it is found that when these novel oximino silanes (tetra-oximino, tris-oximino or bis-oximino) are formulated with hydroxyl terminated polydimethylsiloxane (HTPDMS), an optically clear silicone rubber results.
UsesMethyltris(methylisobutylketoxime)silane is used as a novel neutal curing agent in silicone sealant formulations.
Chemical PropertiesColorless or yellowish transparent liquid
Methyltris(methylisobutylketoxime)silane Preparation Products And Raw materials
Methylparaben Paraquat dichloride Methyl Acetonitrile Tetra-(methylethylketoxime)silane 2-Butanone oxime tert-Butyldimethylsilyl chloride Methyltriethoxysilane Hexamethyldisilane Silicon tetrahydride Methyltrichlorosilane Basic Violet 1 Kresoxim-methyl Methanol Methyl acrylate 4-Methyl-2-pentanone Dichlorodimethylsilane Methyl acetate

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