Bis(2-butoxyethyl)ether

Bis(2-butoxyethyl)ether Basic information
Product Name:Bis(2-butoxyethyl)ether
Synonyms:Butane,1,1’-[oxybis(2,1-ethanediyloxy)]bis-;dibutyletherdiethylenglykolu;Ether, bis(2-butoxyethyl);Ether, bis(butoxyethyl);ether,bis(2-butoxyethyl);ether,bis(butoxyethyl);1,1’-(oxybis(2,1-ethanediyloxy))bis-butan;1,1’-[oxybis(2,1-ethanediyloxy)]bis-butan
CAS:112-73-2
MF:C12H26O3
MW:218.33
EINECS:204-001-9
Product Categories:Functional Materials;Plasticizer;Polyalcohol Ethers, Esters (Plasticizer);bc0001;112-73-2
Mol File:112-73-2.mol
Bis(2-butoxyethyl)ether Structure
Bis(2-butoxyethyl)ether Chemical Properties
Melting point -60 °C (lit.)
Boiling point 256 °C (lit.)
density 0.885 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.423(lit.)
Fp 243 °F
storage temp. Store below +30°C.
solubility 3g/l
form Liquid
color Colorless
Water Solubility 0.3 g/100 mL (20 ºC)
BRN 1750713
LogP1.92 at 25℃
CAS DataBase Reference112-73-2(CAS DataBase Reference)
NIST Chemistry ReferenceButane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-(112-73-2)
EPA Substance Registry SystemDiethylene glycol dibutyl ether (112-73-2)
Safety Information
Safety Statements 23-24/25
WGK Germany 1
RTECS KN0350000
Autoignition Temperature268 °C
TSCA Yes
HS Code 29091900
ToxicityLD50 orally in Rabbit: 3900 mg/kg LD50 dermal Rabbit 3555 mg/kg
MSDS Information
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Bis(2-butoxyethyl)ether Usage And Synthesis
Chemical Propertiesclear colorless to yellowish liquid
UsesExtraction of precious metalsDiethylene glycol dibutyl ether is used as a solvent in Grignard reactions. It is also used as solvents in gold refining, decorative inks for ceramics and digital inks. It finds application in electrochemistry, gas absorption, extractant and high boiling reaction medium. It is also used in fuel, lubricant, textile and medicine.
UsesButyl diglyme is used to extract gold from hydrochloric acid solutions containing other metals. Treatment of the diglyme extract with hydrogen or oxalic acid precipitates the ionic gold as gold powder.
General DescriptionColorless liquid. Floats on water.
Air & Water ReactionsOxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Insoluble in water.
Reactivity ProfileBis(2-butoxyethyl)ether may react violently with strong oxidizing agents. Incompatible with nitric acid. May form salts with strong acids and addition complexes with Lewis acids. In other reactions, which typically involve the breaking of the carbon-oxygen bond, relatively inert.
Health HazardMay be harmful by inhalation, ingestion and skin absorption. Causes eye and skin irritation. Material is irritating to mucous membrane and upper respiratory tract.
Fire HazardSpecial Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back.
Flammability and ExplosibilityNonflammable
Safety ProfileModerately toxic by ingestion. Mddly toxic by skin contact. Experimental reproductive effects. A skin and eye irritant. See also GLYCOL ETHERS. Combustible when exposed to heat or flame. To fight fire, use foam or alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes.
Purification MethodsDibutylcarbitol is freed from peroxides by slow passage through a column of activated alumina. The eluate is then shaken with Na2CO3 (to remove any remaining acidic impurities), washed with water, and stored with CaCl2 in a dark bottle [Tuck J Chem Soc 3202 1957]. [Beilstein 1 IV 2395.]
Bis(2-butoxyethyl)ether Preparation Products And Raw materials
Raw materials1-Butanol-->Diethylene glycol
BIS(2-HYDROXYETHYL) ETHER DILAURATE Ristocetin A sulfate DIETHYLENE GLYCOL DISTEARATE Dicyclohexano-18-crown-6 4,4'(5')-DI-T-BUTYLDICYCLO-HEXANO-18-CROWN-6 1,2:5,6-Di-O-cyclohexylidene-alpha-D-glucofuranose AESCINE BIS[2-(2-BUTOXYETHOXY)ETHYL] ADIPATE 4',4''(5'')-DI-TERT-BUTYLDICYCLOHEXANO-18-CROWN-6 PICROTOXIN DIPROPYLENE GLYCOL DIPELARGONATE DIETHYLENE GLYCOL ABIETATE 2,2'-OXY(DIETHYL DIPELARGONATE) beta-Escin DIETHYLENE GLYCOL DIOLEATE monensin methyl ester Bis(2-butoxyethyl)ether Monensin

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