Methylthioethane

Methylthioethane Basic information
Product Name:Methylthioethane
Synonyms:Methylthioethane (MES);Ethyl methyl thioether;Methylsulfanylethane;2-(Methylthio)ethane;Ethyl methyl sulfide,98%;1-(Methylthio)-ethane;Ethyl Methyl sulfide 96%;methylethylsulfide,(methylthio)-ethane,2-thiabutane
CAS:624-89-5
MF:C3H8S
MW:76.16
EINECS:210-868-4
Product Categories:Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds;Pyrans
Mol File:624-89-5.mol
Methylthioethane Structure
Methylthioethane Chemical Properties
Melting point -106 °C (lit.)
Boiling point 66-67 °C (lit.)
density 0.842 g/mL at 25 °C (lit.)
vapor pressure 272 mm Hg ( 37.7 °C)
FEMA 3860 | METHYL ETHYL SULFIDE
refractive index n20/D 1.440(lit.)
Fp 5 °F
storage temp. Flammables area
form liquid
color Colorless to Light yellow
Specific Gravity0.842
Odorat 0.10 % in propylene glycol. sulfury garlic tomato coffee pyridene cabbage vegetable meaty
Odor Threshold0.00023ppm
Odor Typesulfurous
Water Solubility Miscible with alcohols and oils. Immiscible with water.
JECFA Number453
BRN 1696871
LogP1.54
CAS DataBase Reference624-89-5(CAS DataBase Reference)
NIST Chemistry ReferenceEthane, (methylthio)-(624-89-5)
EPA Substance Registry SystemEthyl methyl sulfide (624-89-5)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-23-24/25
RIDADR UN 1993 3/PG 2
WGK Germany 3
13
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29309090
MSDS Information
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Methylthioethane English
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ACROS English
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Methylthioethane Usage And Synthesis
Chemical Propertiesclear colorless liquid
Chemical PropertiesMethyl ethyl sulfide has a cabbage-like odor.
OccurrenceReported found in tomato, cooked chicken, beef and pork, rum, bourbon, whiskey, cocoa and coffee
UsesEthyl Methyl Sulfide is used as a corrosion inhibitor for zinc metal which finds wide applications like electrode material in batteries, sacrificial anodes and metallic coatings. It is used in mixtures designed to odorize natural gas and is made to by-pass injection system.
Aroma threshold valuesAroma characteristics at 0.1%: sulfurous, tomato and cabbage vegetative with dimethyl sulfide, meaty and metallic nuances.
Taste threshold valuesTaste characteristics at 0.25 to 2 ppm: sulfurous, vegetative, dimethyl sulfide-like sweet corn notes, eggy, meaty and clam nuances
General DescriptionMicrowave spectra of the trans isomer of ethyl methyl sulfide and its 10 isotopic species has been investigated. Chlorination of ethyl methyl sulfide with N-chlorosuccinimide and sulfuryl chloride has been reported.
Methylthioethane Preparation Products And Raw materials
Raw materialsSodium thiomethoxide-->3-(Methylthio)propionaldehyde-->Di-tert-butyl peroxide-->METHYL MERCAPTAN
Preparation Products2-CHLOROETHYL METHYL SULFIDE
Hydrogen Sulfide Methylparaben METHYL (METHYLSULFINYL)ACETATE,80% TECH. Methyl Bensulfuron methyl METHYL ETHYLCELLULOSE Methyl 2-hydroxyethyl cellulose Sodium sulfide CARBONYL SULFIDE 2-Butanone Kresoxim-methyl Dimethyl sulfide Diethyl ether DI-N-BUTYL SULFOXIDE 4-CHLOROPHENYL 2-CHLORO-1,1,2-TRIFLUOROETHYL SULFONE Methyl acrylate Methylthioethane 1,1'-Thiobisethane

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