3-Decyn-1-ol

3-Decyn-1-ol Basic information
Product Name:3-Decyn-1-ol
Synonyms:TIMTEC-BB SBB008896;2-HYDROXYETHYL-N-HEXYLACETYLENE;3-DECYN-1-OL;3-Decyne-1-ol;2-Hydroxyethylhexylacetylene;Ai3-37272;Hexyl(2-hydroxyethyl)acetylene;Dec-3-yn-1-ol
CAS:51721-39-2
MF:C10H18O
MW:154.25
EINECS:
Product Categories:Building Blocks;Chemical Synthesis;Organic Building Blocks;Acetylenes;Acetylenic Alcohols & Their Derivatives;Alkynes;Organic Building Blocks;Terminal
Mol File:51721-39-2.mol
3-Decyn-1-ol Structure
3-Decyn-1-ol Chemical Properties
Melting point 1.9°C (estimate)
Boiling point 130-131 °C/22 mmHg (lit.)
density 0.877 g/mL at 25 °C (lit.)
refractive index n20/D 1.459(lit.)
Fp 224 °F
pka14.41±0.10(Predicted)
form clear liquid
color Colorless to Light orange to Yellow
Specific Gravity0.877
Water Solubility Sparingly soluble in water (0.21 g/L) (25°C).
BRN 1750909
CAS DataBase Reference51721-39-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2905.29.9000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-Decyn-1-ol Usage And Synthesis
Uses3-Decyn-1-ol may be used in the following studies, as a starting material in the synthesis of 3?-deoxyribolactones, as a starting material in the synthesis of (Z)-3-decen-1-ol by hydrogenation over P-2 nickel and as a reagent in the synthesis of methyl 9-decynoate.
Uses3-Decyn-1-ol may be used in the following studies:
  • As a starting material in the synthesis of 3′-deoxyribolactones.
  • As a starting material in the synthesis of (Z)-3-decen-1-ol by hydrogenation over P-2 nickel.
  • As a reagent in the synthesis of methyl 9-decynoate.
Synthesis Reference(s)Tetrahedron Letters, 25, p. 5423, 1984 DOI: 10.1016/S0040-4039(01)91301-2
General Description3-Decyn-1-ol is primary homo-propargylic alcohol derivative. It has been reported to be formed during the isomerization of 2-decyn-1-ol in the presence of sodium salt of 1,3-diaminopropane. Its toxicity has been evaluated on the green alga, Pseudokirchneriella subcapitata in terms of EC50 (median effective concentration) and NOEC (no observed effect level) values. It undergoes semi hydrogenation in the presence of Lindlar catalyst to form cis-3-decen-1-ol.
3-Decyn-1-ol Preparation Products And Raw materials
Preparation Products(Z)-3-decenol-->TRANS-3-DECENE-->Peachflure
7-Decyn-1-ol (1S)-1-[(R)-1-Methyl-2-propenyl]-2-decyn-1-ol 2-Ethenyl-3-decyn-1-ol 3-DECYNE 1,3-BIS(1'-HYDROXYCYCLOHEXYL)-1-PROPYNE 3-TETRADECYN-1-OL (S)-3-Decyn-2-ol 9-DECYN-1-OL,2-DECYN-2-OL (1S)-1-[(S)-1-Methyl-2-propenyl]-2-decyn-1-ol 4-Decyn-2-ol 1-Decyn-4-ol 5-Decyn-1-ol acetate 10-Chloro-3-decyn-1-ol alfaprostol (1S)-1-(2-Propenyl)-2-decyn-1-ol 13,14-DEHYDRO-15-CYCLOHEXYL CARBAPROSTACYCLIN 2-Methyl-4-decyn-2-ol 3-Decyn-2-ol

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