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| | Allyltrimethoxysilane Basic information |
| | Allyltrimethoxysilane Chemical Properties |
| Boiling point | 146-148 °C (lit.) | | density | 0.963 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.405(lit.) | | Fp | 88 °F | | storage temp. | Inert atmosphere,2-8°C | | form | Liquid | | color | Clear colorless | | Specific Gravity | 0.96 | | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | | BRN | 2350745 | | InChIKey | LFRDHGNFBLIJIY-UHFFFAOYSA-N | | EPA Substance Registry System | Silane, trimethoxy-2-propenyl- (2551-83-9) |
| Hazard Codes | Xi | | Risk Statements | 10-36/37/38 | | Safety Statements | 26-36-37/39-16 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | F | 10-21 | | TSCA | Yes | | HazardClass | 3.1 | | PackingGroup | II | | HS Code | 29319090 |
| | Allyltrimethoxysilane Usage And Synthesis |
| Chemical Properties | Colorless to Almost colorless clear liquid to slightly cloudy liquid | | Uses | Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones. | | Application | Allyltrimethoxysilane as the Reagent of Double Bond Introduction to Porous Silica for Preparation of a Chiral Stationary Phase in Comparison with Allyltriethoxysilane.
Allylation of ketones, aldehydes and imines with dual activation of a Lewis Acid and fluoride ion.
Used in the regioselective generation of the thermodynamically more stable enol trimethoxysilyl ethers, which in turn are used in the asymmetric generation of quaternary carbon centers.
Converts arylselenyl bromides to arylallylselenides.
Allylates aryl iodides.
Allyltrimethoxysilane serves as a remarkable reagent in Silver-Catalyzed Asymmetric Allylation. |
| | Allyltrimethoxysilane Preparation Products And Raw materials |
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