ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic ketones 2-Isonitrosoacetophenone

2-Isonitrosoacetophenone

2-Isonitrosoacetophenone Basic information
Product Name:2-Isonitrosoacetophenone
Synonyms:ω-(Hydroxyimino)acetophenone, ω-Isonitrosoacetophenone, Phenylglyoxaldoxime;Phenylglyoxal monoxime;Benzoylformoxime;Phenylglyoxal oxime;α-Oxobenzeneacetaldehyde oxime;2-Isonitrosoacetophenone,99%;Benzoylformaldoxime 2-Hydroxyiminoacetophenone;(E)-2-oxo-2-phenylacetaldehyde oxiMe
CAS:532-54-7
MF:C8H7NO2
MW:149.15
EINECS:208-539-5
Product Categories:Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Oximes
Mol File:532-54-7.mol
2-Isonitrosoacetophenone Structure
2-Isonitrosoacetophenone Chemical Properties
Melting point 126-128 °C (lit.)
Boiling point 270.21°C (rough estimate)
density 1.2517 (rough estimate)
refractive index 1.5320 (estimate)
storage temp. 2-8°C
pka8.49±0.10(Predicted)
form powder to crystal
color White to Light yellow to Light orange
Water Solubility SOLUBLE IN COLD WATER
Merck 14,5191
BRN 2041691
CAS DataBase Reference532-54-7(CAS DataBase Reference)
EPA Substance Registry SystemIsonitrosoacetophenone (532-54-7)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 20/21/22-36/37/38
Safety Statements 36/37-24/25
RIDADR 2811
WGK Germany 3
RTECS MD3325000
TSCA Yes
HS Code 2922390090
MSDS Information
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2-Isonitrosoacetophenone English
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2-Isonitrosoacetophenone Usage And Synthesis
Chemical Propertiesbeige to yellowish crystalline powder
UsesAs a reagent for the detection of ferrous ions with which it gives a blue color soluble in chloroform.
Uses2-Isonitrosoacetophenone is used to make a complex with copper and amino acids. These complexes has shown to have more antimicrobial activities against gram positive bacteria than gram negative bacteria and the complexes also have antioxidant activity.
Synthesis Reference(s)The Journal of Organic Chemistry, 39, p. 2558, 1974 DOI: 10.1021/jo00931a022
Purification MethodsCrystallise it from water. [Beilstein 7 IV 2132.]
2-Isonitrosoacetophenone Preparation Products And Raw materials
Preparation Products2-Aminoecetophenone-->2-METHYL-2-NONYL-4-PHENYL-2H-IMIDAZOLE-1-OXIDE, FREE RADICAL, 99+%
1-PHENYL-1,2,3-BUTANETRIONE 2-OXIME 4'-Bromoacetophenone 1-Phenyl-1,2-propanedione-2-oxime 1-(4-FLUORO-PHENYL)-BUTANE-1,2-DIONE 2-OXIME 4-Hydroxy-alpha-oxo-benzeneacetaldehydealdoxime 1-(4-CHLORO-PHENYL)-PROPANE-1,2-DIONE 2-OXIME 4-CHLOROPHENYLGLYOXYLOHYDROXAMYL CHLORIDE 4-Nitroacetophenone (4-METHYLPHENYL)(OXO)ACETALDEHYDE OXIME 2',4'-Dichloroacetophenone (4-BROMO-PHENYL)-OXO-ACETALDEHYDE OXIME 2-(2-PYRIDYL)-3H-INDOL-3-ONE N-OXIDE 2-Isonitrosoacetophenone 2-[[(ETHOXYCARBONYL)OXY]IMINO]-1,2-DIPHENYLETHAN-1-ONE 1-(4-Chlorophenyl)-2-(hydroxyimino)ethanone 1-P-TOLYL-PROPANE-1,2-DIONE 2-OXIME (4-NITROPHENYL)-OXO-ACETALDEHYDE OXIME B-BENZILMONOXIME
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