FLUOROIMIDE

FLUOROIMIDE Basic information
Product Name:FLUOROIMIDE
Synonyms:3,4-DICHLORO-1-(4-FLUORO-PHENYL)-PYRROLE-2,5-DIONE;FLUOROIMIDE;OTAVA-BB BB7014250005;2,3-dichloro-n-4-fluorophenylmaleimide;3,4-dichloro-1-(4-fluorophenyl)-1h-pyrrole-2,5-dione;3,4-dichloro-1-(4-fluorophenyl)-1h-pyrrole-5-dione;mk23;n-p-fluorophenyl-2,3-dichloromaleimide
CAS:41205-21-4
MF:C10H4Cl2FNO2
MW:260.05
EINECS:
Product Categories:
Mol File:41205-21-4.mol
FLUOROIMIDE Structure
FLUOROIMIDE Chemical Properties
Melting point 238~242℃
Boiling point 324.7±42.0 °C(Predicted)
density 1.63±0.1 g/cm3(Predicted)
vapor pressure 3.4 x 10-3 Pa (25 °C)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Sparingly), Methanol (Slightly)
pka-4.79±0.60(Predicted)
form Solid
Water Solubility 5.9 mg l-1 (20 °C)
color Off-White to Light Yellow
Safety Information
Hazard Codes T,N
Risk Statements 23-41-51/53
Safety Statements 26-39-45-61
RIDADR UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all
MSDS Information
FLUOROIMIDE Usage And Synthesis
Chemical Propertiesyellow crystalline powder
UsesFluoroimide is used to control Monilinia mali and Mycosphaerella pomi in apples, Diaporthe citri and Elsinoe fawcetti in citrus, Corticium spp. in rubber trees, Botryfis cinerea and Peronospora destructor in onions, Colletotrichum theae-sinensis and Exobasidium vexans in tea, Phytophthora infestans in potatoes at 2-5 kg a.i. ha-1 and Cercospora kaki and Mycosphaerella mwae in persimmons at 0.5-2 kg ha-1.
DefinitionChEBI: A maleimide that is substituted at positions 3 and 4 by chlorines and on the nitrogen by a p-fluorophenyl group. Previously used as a fungicide (now obsolete).
Metabolic pathwayFluoroimide is a relatively volatile solid with a high melting point. It degrades to a range of products in soils and plants. The main pathways are hydrolysis of the amide bond causing scission of the maleimide ring and stepwise reduction involving dechlorination of the maleimide ring. Little transformation of the parent fungicide occurred on plants.
DegradationHydrolysis of fluoroimide is base catalysed. The DT50 values for the hydrolysis are 52.9,7.5 and 1.4 minutes at pH 3,7 and 8, respectively. The fungicide is stable to sunlight (PM).
FLUOROIMIDE Preparation Products And Raw materials
N-Chloroethyl-N-ethylaniline 3,4-DICHLORO-1-(3,4-DIFLUOROPHENYL)-1H-PYRROLE-2,5-DIONE 3,4-DICHLORO-1-(3-CHLORO-4-FLUORO-PHENYL)-PYRROLE-2,5-DIONE 4-FLUORO-N,N-DIMETHYLANILINE N-PENTAFLUOROPHENYLDICHLOROMALEIMIDE N,N-BIS(2-CHLOROETHYL)ANILINE 1-(4-FLUORO-PHENYL)-PYRROLE-2,5-DIONE 3-Pyrroline N-ACETYL-2-CHLORO-ACETAMIDE 2-CHLORO-N-METHYL-N-PHENYLACETAMIDE 2,3-DICHLORO-N-METHYLMALEIMIDE 2-chloro-N-ethyl-N-methylacetamide N-ETHYL-P-FLUOROANILINE HYDROCHLORIDE CIS-1,2-DICHLOROETHYLENE N-(2-CHLOROETHYL)ACETAMIDE Nornitrogen mustard FLUOROIMIDE Chlormethine

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