PHENYLMERCURIC CHLORIDE

PHENYLMERCURIC CHLORIDE Basic information
Product Name:PHENYLMERCURIC CHLORIDE
Synonyms:(chloromercuri)-benzen;(chloromercurio)-benzen;Agrenal;Agronal;Benzene, (chloromercuri)-;Benzene, (chloromercurio)-;Chlorid fenylrtutnaty;chloridfenylrtutnaty
CAS:100-56-1
MF:C6H5ClHg
MW:313.15
EINECS:202-865-1
Product Categories:organomercury compound;Organomercury;Organometallic Reagents;Others;Mercury compoundsPesticides&Metabolites;Alpha sort;Fungicides;N-POrganometallic Reagents;OrganomercuryAlphabetic;P;PER - POLA;Pesticides
Mol File:100-56-1.mol
PHENYLMERCURIC CHLORIDE Structure
PHENYLMERCURIC CHLORIDE Chemical Properties
Melting point 248-250 °C (dec.)(lit.)
storage temp. Poison room
solubility soluble in DMSO
form solid
Water Solubility Soluble in benzene, ether, pyridine. Very slightly soluble in water
Merck 14,7301
BRN 3536717
Exposure limitsACGIH: TWA 0.1 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
CAS DataBase Reference100-56-1(CAS DataBase Reference)
EPA Substance Registry SystemMercury, chlorophenyl- (100-56-1)
Safety Information
Hazard Codes T+,N
Risk Statements 26/27/28-33-50/53
Safety Statements 13-28-36-45-60-61
RIDADR UN 2026 6.1/PG 3
WGK Germany 3
RTECS OW1400000
HazardClass 6.1
PackingGroup II
HS Code 28439090
Hazardous Substances Data100-56-1(Hazardous Substances Data)
ToxicityLD50 s.c. in rats: 30 mg/kg (Umeda)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
PHENYLMERCURIC CHLORIDE Usage And Synthesis
Chemical Propertieswhite fine crystalline powder
UsesPhenylmercuric chloride has been used as an agricultural fungicide.
UsesThe reaction of phenylmercury (II) chloride with acetophenonethiosemicarbazone (Hatsc) in ethanol in 1: 1 mole ratio undergoes symmetrisation forming the products, HgCl2 (Hatse) 2 and Ph2Hg instead of the anticipated compound PhHgCl (Hatse). A new method for the determination of chloride ion is based on the formation of phenylmercury(II) chloride, its extraction into chloroform and reaction with sodium diethyldithiocarbamate to form phenylmercury(II) diethyldithiocarbamate.
Safety ProfilePoison by ingestion, intraperitoneal, and subcutaneous routes. Human mutation data reported. When heated to decomposition ir emits very toxic fumes of Cland Hg. See also MERCURY COMPOUNDS and CHLORIDES.
PHENYLMERCURIC CHLORIDE Preparation Products And Raw materials
Preparation Productsphenyl(tribromomethyl)mercury
Mercury chloride MERCURY ORANGE 4-CHLOROMERCURIBENZOIC ACID SODIUM SALT 4-CHLOROMERCURIBENZOIC ACID mercurobutol P-TOLYLMERCURIC CHLORIDE 4-CHLOROMERCURIPHENOL 4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt 2-CHLOROMERCURI-4-NITROPHENOL Mercury 2-(CHLOROMERCURI)PHENOL PHENYLMERCURIC CHLORIDE

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