BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE

BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Basic information
Product Name:BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE
Synonyms:SPECTRASYNQ 443;ULTRAMARK 443;Bis(pentafluorophenyl)phenylphosphine, tech., 90%;decafluorotriphenylphosphine solution;dftpp solution;BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE;DI(2,3,4,5,6-PENTAFLUOROPHENYL)(PHENYL)PHOSPHINE;2,3,4,5,6,2',3',4',5',6'-DECAFLUOROTRIPHENYLPHOSPHINE
CAS:5074-71-5
MF:C18H5F10P
MW:442.19
EINECS:225-780-1
Product Categories:Ligand
Mol File:5074-71-5.mol
BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Structure
BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Chemical Properties
Melting point 55-60 °C (lit.)
Boiling point 105°C/0.3mm
Fp >230 °F
storage temp. room temp
solubility Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.
form Powder
color white
Sensitive air sensitive
BRN 6253897
CAS DataBase Reference5074-71-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn,T,F
Risk Statements 36/37/38-20/21/22-40-63-43-23/24/25-45-67-66-36/38-11-36
Safety Statements 26-36/37/39-22-36/37-24/25-23-53-16-9
RIDADR UN 1593 6.1/PG 3
WGK Germany 3
Hazard Note Irritant
TSCA No
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesBis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.
General DescriptionDecafluorotriphenylphosphine (DFTPP) is commonly used as a check standard for the calibration of mass spectrum detector (MSD) prior to the analysis of samples under investigation.
BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Preparation Products And Raw materials
Phenyl phosphine Pentafluorobenzene (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Phosphine

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