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| | 1,6-Dibromopyrene Basic information |
| Product Name: | 1,6-Dibromopyrene | | Synonyms: | 6-DibroMopyrene;Pyrene, 1,6-dibromo-;1,6-Dibromopyrene;1,6-dlbrornopyrone;1,6-Dibromopyrene>;1,6-Dibromopyrene ISO 9001：2015 REACH | | CAS: | 27973-29-1 | | MF: | C16H8Br2 | | MW: | 360.04 | | EINECS: | 1308068-626-2 | | Product Categories: | fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis;intermediate;OLED;OLED materrials | | Mol File: | 27973-29-1.mol |  |
| | 1,6-Dibromopyrene Chemical Properties |
| Melting point | 228.0 to 232.0 °C | | Boiling point | 469.6±18.0 °C(Predicted) | | density | 1.852±0.06 g/cm3(Predicted) | | storage temp. | Sealed in dry,Room Temperature | | solubility | Chloroform (Very Slightly, Heated), Methanol (Very Slightly, Heated) | | form | Solid | | color | White to Off-White | | λmax | 246nm(EtOH)(lit.) |
| | 1,6-Dibromopyrene Usage And Synthesis |
| Description | 1, 6-dibromopyrene is a kind of pyrene chemical. It is majorly used
as organic intermediate, OLED (organic light-emitting diodes)
materials and photoelectric material. It, together with its 1, 8-
isomer, can be produced by the double bromination of pyrene with
bromine. It can be applied to the synthesis of bipyridine and
terpyridine based ruthenium metallosynthons. | | Chemical Properties | white powder | | References | Goze, Christine, et al. "Synthesis of bipyridine and terpyridine based ruthenium metallosynthons for grafting of multiple pyrene auxiliaries."Tetrahedron letters 44.48 (2003): 8713-8716.
Kaplunov, Mikhail G., et al. "Novel 1, 8-bis(diarylamino)pyrenes as OLED materials." Mendeleev Communications 26.5(2016):437-439.
Gong, Xiaojie, et al. "Two Symmetrically Bis‐substituted Pyrene Derivatives: Synthesis, Photoluminescence, and Electroluminescence." Chinese Journal of Chemistry 33.8 (2015): 967-973.
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| | 1,6-Dibromopyrene Preparation Products And Raw materials |
| Raw materials | [1,1'-Biphenyl]-2,2'-diamine, 3,3'-dibromo--->1,3,6-tribromopyrene-->1,8-Dibromopyrene-->1-bromo-3-(3-bromophenyl)benzene-->1-Bromopyrene-->1,3-Dibromo-5,5-dimethylhydantoin-->Pyrene | | Preparation Products | Pyrene, 1,3-dibromo--->1,6-dimethylpyrene |
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