Allyl ether

Allyl ether Basic information
Product Name:Allyl ether
Synonyms:Allylic Ether;Allyl ether,99%;Allyl ether 98%;Bis(2-propenyl)ether;Ether, diallyl;ether,diallyl;ether,propenyl;propenylether
CAS:557-40-4
MF:C6H10O
MW:98.14
EINECS:209-174-4
Product Categories:
Mol File:557-40-4.mol
Allyl ether Structure
Allyl ether Chemical Properties
Melting point -6°C
Boiling point 94 °C
density 0.803 g/mL at 25 °C(lit.)
refractive index 1.415-1.417
Fp -7 °C
storage temp. Refrigerator (+4°C) + Flammables area
solubility Chloroform, Methanol (Slightly)
form clear liquid
color Colorless to Almost colorless
Water Solubility insoluble
Merck 14,292
CAS DataBase Reference557-40-4(CAS DataBase Reference)
NIST Chemistry Reference(CH2=CHCH2)2O(557-40-4)
EPA Substance Registry System1-Propene, 3,3'-oxybis- (557-40-4)
Safety Information
Hazard Codes Xn-F,Xn,F
Risk Statements 36/37/38-20/21/22-11
Safety Statements 9-36/37/39-33-26-16-45
RIDADR 2360
WGK Germany 3
RTECS KN7525000
HS Code 2909.19.1800
HazardClass 3.1
PackingGroup II
ToxicityLD50 orally in rats: 0.32 g/kg (Smyth)
MSDS Information
ProviderLanguage
ACROS English
Allyl ether Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesAllyl Ether is a modifier used in the manufacture of foamable polystyrene.
General DescriptionA liquid with an odor of radishes. Less dense than water. Flash point 20°F. May be toxic by ingestion, skin absorption, and inhalation, and may irritate skin and eyes. Vapors heavier than air. Used to make other chemicals.
Air & Water ReactionsHighly flammable. Soluble in water. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154].
Reactivity ProfileEthers, such as DIALLYLETHER can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Health HazardTOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety ProfilePoison by ingestion. Moderately toxic by skin contact. A skin and eye irritant. A dangerous fire hazard when exposed to heat, flame, or oxidzing materials. To fight fire, use alcohol foam. Reacts with air to form explosive peroxides. Violent explosions have occurred during distillation. When heated to decomposition it emits acrid smoke and fumes. See also ALLYL COMPOUNDS and ETHERS.
Allyl ether Preparation Products And Raw materials
Preparation ProductsEugenol-->Nedocromil-->[[o-(allyloxy)phenoxy]methyl]oxirane-->ALLYL BUTYL ETHER-->ALLYL BENZOATE
(2,6-Dimethoxyphenyl)allyl ether 2,4,6-Trimethylolphenyl allyl ether 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl(allyl) ether 2,2',6,6'-Tetrabromobisphenol A diallyl ether 2-CYCLOPENTEN-1-YL ETHER, 98 Propargyl allyl ether (2-Ethoxyphenyl)allyl ether Allyldiglycol 2-CHLORO-1,1,2-TRIFLUOROETHYL ALLYL ETHER S-Bioallethrin (3-Bromophenyl)allyl ether (tert-Butyldimethylsilyl)[2-(tributylstannyl)allyl] ether Sodium allylsulfonate 2H-HEXAFLUOROPROPYL ALLYL ETHER Crotonic anhydride rich_d_transallethrin Propyl allyl ether 2,4-Di(hydroxymethyl)phenyl allyl ether,2,4-Dimethylolphenyl allyl ether

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