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| | Ferric acetylacetonate Basic information |
| | Ferric acetylacetonate Chemical Properties |
| Melting point | 180-182 °C (dec.)(lit.) | | Boiling point | 110°C 2mm | | density | 5.24 g/mL at 25 °C(lit.) | | vapor pressure | 2.6 hPa (110 °C) | | storage temp. | Store below +30°C. | | solubility | Soluble in toluene. | | form | Powder | | color | Red | | Specific Gravity | 5.24 | | Water Solubility | 2 g/L (20 ºC) | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | BRN | 4157960 | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | | Stability: | Stable. Incompatible with strong bases, strong oxidizing agents. | | LogP | 0.4 at 20℃ | | NIST Chemistry Reference | Iron tris(acetylacetonate)(14024-18-1) | | EPA Substance Registry System | Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1) |
| Hazard Codes | Xn | | Risk Statements | 22-36 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | RTECS | NO8960000 | | F | 21 | | TSCA | Yes | | HS Code | 29420000 | | Toxicity | LD50 orally in Rabbit: 1872 mg/kg |
| | Ferric acetylacetonate Usage And Synthesis |
| Chemical Properties | dark red powder or Red-orange orthorhombic crystal, slightly soluble in water and heptane, easily soluble in ethanol, benzene, chloroform, acetone and ether. Solubility at 25°C: water 0.16, methanol 9.5, toluene 21.3, benzene 52.5. | | Uses | Moderating and combustion catalyst, solid fuel
catalyst, bonding agent, curing accelerator, intermediate. | | Uses | Iron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe2O4 | | Uses | Chemical Synthesis of Monodisperse Magnetic Nanoparticles | | Preparation | Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states. | | General Description | This product has been enhanced for catalytic efficiency. | | Flammability and Explosibility | Notclassified | | Purification Methods | When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr [Finn et al. J Chem Soc 1256 1938]. However, when recrystallised from EtOH or Et2O it has m 179o [Hantzsch & Desch Justus Liebigs Ann Chem 323 13 1902]. Recrystallisation from absolute EtOH gives material with m 159.5o [Emmert & Jacob Chem Ber 67 286 1934]. Dry it for 1hour at 120o. [Beilstein 1 IV 606, 2 IV 1908.] |
| | Ferric acetylacetonate Preparation Products And Raw materials |
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