2-Fluorotoluene

2-Fluorotoluene Basic information

Product Name:	2-Fluorotoluene
Synonyms:	1-Fluor-2-methylbenzol;1-fluoro-2-methyl-benzen;1-fluoro-2-methyl-benzene;1-Methyl-2-fluorobenzene;2-fluoromethylbenzene;2-FLUOROTOLUENE;Benzene,1-fluoro-2-methyl-;benzene,2-fluoro-1-methyl-
CAS:	95-52-3
MF:	C7H7F
MW:	110.13
EINECS:	202-428-5
Product Categories:	Aryl Fluorinated Building Blocks;Building Blocks;C7-C8;Chemical Synthesis;Fluorinated Building Blocks;Halogenated Hydrocarbons;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;alkyl Fluorine;organofluorine compounds;Aromatic Hydrocarbons (substituted) & Derivatives;Organics;Aryl;C7;Halogenated Hydrocarbons
Mol File:	95-52-3.mol

2-Fluorotoluene Chemical Properties

Melting point	-62 °C (lit.)
Boiling point	113-114 °C (lit.)
density	1.001 g/mL at 25 °C (lit.)
vapor density	3.8 (vs air)
vapor pressure	21 mm Hg ( 20 °C)
refractive index	n20/D 1.473(lit.)
Fp	55 °F
storage temp.	Store below +30°C.
form	Liquid
Specific Gravity	1.001
color	Clear colorless to slightly yellow
explosive limit	1.3%(V)
Water Solubility	immiscible
Merck	14,4180
BRN	1853362
LogP	2.73-2.74
CAS DataBase Reference	95-52-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-fluoro-2-methyl-(95-52-3)
EPA Substance Registry System	o-Fluorotoluene (95-52-3)

Safety Information

Hazard Codes	F,Xi
Risk Statements	11-36/37/38
Safety Statements	16-26-33-36-37/39
RIDADR	UN 2388 3/PG 2
WGK Germany	3
RTECS	XT2579000
Hazard Note	Flammable/Irritant
TSCA	Yes
HazardClass	3
PackingGroup	II
HS Code	29036990
Toxicity	LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg

MSDS Information

Provider	Language
2-Fluorotoluene	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Fluorotoluene Usage And Synthesis

Chemical Properties	clear colorless to slightly yellow liquid
Uses	It is employed in organic synthesis.
General Description	A colorless liquid with an aromatic odor. May sink or float on water.
Air & Water Reactions	Highly flammable. Insoluble in water.
Reactivity Profile	2-Fluorotoluene is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999].
Health Hazard	Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects.
Purification Methods	Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]

2-Fluorotoluene Preparation Products And Raw materials

Raw materials	2-Chlorotoluene-->3-Fluorotoluene
Preparation Products	2-Fluorobenzoyl chloride-->2-Fluoro-5-nitrotoluene-->2-FLUORO-3-NITROBENZOIC ACID-->alpha-Chloro-o-fluorotoluene-->Cyclopropyl 2-fluorobenzyl ketone-->4-acetyl-2-methylbenzoic acid-->2-TERT-BUTYL-1H-INDOLE-->7-METHYL (1H)INDAZOLE-->2-Fluorostyrene-->2-METHYLPHENYLBORONIC ACID, PINACOL ESTER-->2-Fluoro-3-methylBenzonitrile-->o-fluorocinnamic acid-->2-Fluoro-5-nitrobenzoic acid-->p-Fluorotoluene

3-Bromo-6-chloro-2-fluorotoluene 3-Amino-5-fluorobenzotrifluoride Tosufloxacin tosylate 3,5-Diaminobenzotrifluoride 3-Amino-5-fluorotoluene 4-BROMOFLUOROBENZENE & A,A,A-TRIFLUOROTOLUENE 3-Bromo-2-fluoro-6-fluorotoluene 3-CHLORO-4,5-DIAMINOBENZOTRIFLUORIDE 2,4-DIBROMO-5-FLUOROTOLUENE 2-CHLORO-3-FLUOROTOLUENE 2',3',4',5',6'-PENTAFLUOROACETOPHENONE 4,4'-DIMETHYLOCTAFLUOROBIPHENYL 3-Bromo-4-chloro-5-fluorotoluene PENTAFLUOROBENZYL BROMIDE 4-Amino-2-fluorobenzotrifluoride à-bromo-3-chloro-6-fluorotoluene 2.3-DIFLUORO 4-TRIFLUOROMETHOXYANILINE 3-Bromo-2-fluorotoluene 98%

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