N-(TERT-BUTOXYCARBONYL)-2-BROMOANILINE

N-(TERT-BUTOXYCARBONYL)-2-BROMOANILINE Basic information
Product Name:N-(TERT-BUTOXYCARBONYL)-2-BROMOANILINE
Synonyms:TERT-BUTYL N-(2-BROMOPHENYL)CARBAMATE;N-Boc 2-broMoaniline;tert-butyl (2-broMophenyl)carbaMate;2-Bromo-N-(tert-butoxycarbonyl) aniline;N-(tert-Butoxycarbonyl)-2-bromoaniline 97%;tert-Butyl (2-bromophenyl);Carbamic acid, N-(2-bromophenyl)-, 1,1-dimethylethyl ester;ert-butylN-(2-bromophenyl)carbamate
CAS:78839-75-5
MF:C11H14BrNO2
MW:272.14
EINECS:
Product Categories:Nitrogen Compounds;Organic Building Blocks;Protected Amines;amine|alkyl bromide| carboxylic ester
Mol File:78839-75-5.mol
N-(TERT-BUTOXYCARBONYL)-2-BROMOANILINE Structure
N-(TERT-BUTOXYCARBONYL)-2-BROMOANILINE Chemical Properties
Boiling point 110 °C0.3 mm Hg(lit.)
density 1.342 g/mL at 25 °C(lit.)
refractive index n20/D 1.54(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
pka12.93±0.70(Predicted)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
N-(TERT-BUTOXYCARBONYL)-2-BROMOANILINE Usage And Synthesis
UsesN-(tert-Butoxycarbonyl)-2-bromoaniline may be used in the synthesis of N-boc-protected o-aryl anilines, which undergoes coupling reaction with bromoacetylenes to form the corresponding arene?ynamides.
General DescriptionN-(tert-Butoxycarbonyl)-2-bromoaniline, also known as tert-butyl-N-(2-bromophenyl)carbamate, is an N-Boc-protected o-bromoaniline.1 It reacts with ethyl perfluorooctanoate in the presence of tert-butyllithium to form the corresponding 1-hydroxy-1H-perfluorooctyl compound.

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