2-AMINOBENZYLAMINE

2-AMINOBENZYLAMINE Basic information
Product Name:2-AMINOBENZYLAMINE
Synonyms:RARECHEM AL BW 0101;ALPHA-AMINO-O-TOLUIDINE;AKOS AUF2060;2-AMINOBENZYLAMINE;2-AMINOBENZYLAMINE 98+%;2-Aminobenzenemethanamine;2-(aminomethyl)aniline dihydrochloride;Albb-006006
CAS:4403-69-4
MF:C7H10N2
MW:122.17
EINECS:
Product Categories:Nitrogen Compounds;Organic Building Blocks;Polyamines;Anilines, Aromatic Amines and Nitro Compounds
Mol File:4403-69-4.mol
2-AMINOBENZYLAMINE Structure
2-AMINOBENZYLAMINE Chemical Properties
Melting point 58-61 °C (lit.)
Boiling point 98 °C / 1.5mmHg
density 1.0343 (rough estimate)
refractive index 1.5103 (estimate)
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form powder to crystal
pka9.60±0.10(Predicted)
color White to Almost white
CAS DataBase Reference4403-69-4(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 22-34
Safety Statements 26-36/37/39-45
RIDADR UN 3259 8/PG 2
WGK Germany 3
HS Code 2921.59.8090
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
2-AMINOBENZYLAMINE Usage And Synthesis
Uses2-Aminobenzylamine may be used:
  • in the synthesis of 1,2,3,4-tetrahydroquinazoline oxime, via condensation reaction with 2-(naphthalen-2-yl)-2-oxoacetaldehyde oxime
  • in the synthesis of alkyl 5H-1,4-benzodiazepine-3-carboxylates
  • to modify the phosphate groups on phosphoserine peptides
Synthesis Reference(s)Synthesis, p. 695, 1980 DOI: 10.1055/s-1980-29174
General Description2-Aminobenzylamine undergoes three-component cyclisation reactions with methyl 3,3,3-trifluoropyruvate, 2-aminobenzylamine and oxo compounds to afford regio- and stereoisomers of tetrahydropyrroloquinazolinones.
2-AMINOBENZYLAMINE Preparation Products And Raw materials
Preparation ProductsQuinazoline-->2-(2-chlorophenyl)quinazoline-->2,2'-Biquinazoline-->1,4-dihydro-2-quinazolinamine-->tert-butyl 4-(2-aMinobenzylaMino)piperidine-1-carboxylate
2-METHYL-4(3H)-QUINAZOLINONE 1,2-DIHYDRO-5-NITROINDAZOL-3-ONE [4-CHLORO-2-(1,2,3,4-TETRAHYDRO-ISOQUINOLIN-1-YL)-PHENYL]-METHYL-AMINE 2-MERCAPTO-4(3H)-QUINAZOLINONE (-)-1-[5-CHLORO-2-(METHYLAMINO)PHENYL]-1,2,3,4-TETRAHYDROISOQUINOLINE,(-)-TARTRATE 2-(TRICHLOROMETHYL)QUINAZOLIN-4(3H)-ONE 3-Nitrophthalhydrazide TRYPTANTHRIN N-methyl-4-(N,N-dimethylamino)benzylamine N-Ethyl-4-aminobenzylamine 3-(Methylsulfonylamino)benzylamine Hydrochloride 2-AMINO-5-NITROBENZANILIDE S-(-)-a-Methyl-p-aminobenzylamine 2-NITROBENZANILIDE 2-Aminobenzylamine dihydrochloride,o-Aminobenzylamine dihydrochloride,O-AMINOBENZYLAMINE 2HCL N-ethyl-4-(dimethylamino)benzylamine Dihydrochloride 3-INDAZOLINONE 4-DIMETHYLAMINOBENZYLAMINE

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