3-METHOXYBENZYL BROMIDE

3-METHOXYBENZYL BROMIDE Basic information

Product Name:	3-METHOXYBENZYL BROMIDE
Synonyms:	3-(BroMoMethyl)phenyl Methyl Ether;3-Methoxy-1-(broMoMethyl)benzene;3-Methoxylbenzyl BroMide;3-Methoxyphenyl)Methyl broMide;M-(BroMoMethyl)anisole;1-(BroMMethyl)-3-Methoxybenzol;3-(Bromomethyl)anisole, 1-(Bromomethyl)-3-methoxybenzene, 3-(Bromomethyl)phenyl methyl ether;3-Methoxybenzyl broMide, 98+%, 98+%
CAS:	874-98-6
MF:	C8H9BrO
MW:	201.06
EINECS:
Product Categories:	Methyl Halides;Phenyls & Phenyl-Het;Methyl Halides;Phenyls & Phenyl-Het;Aromatics;Catalyst;Intermediates & Fine Chemicals;Pharmaceuticals
Mol File:	874-98-6.mol

3-METHOXYBENZYL BROMIDE Chemical Properties

Boiling point	152 °C(lit.)
density	1.436 g/mL at 25 °C(lit.)
refractive index	n20/D 1.575(lit.)
Fp	>230 °F
storage temp.	-20°C Freezer
solubility	soluble in Chloroform
form	Liquid
color	Clear colorless to light yellow
CAS DataBase Reference	874-98-6(CAS DataBase Reference)

Safety Information

Hazard Codes	C
Risk Statements	34
Safety Statements	26-27-36/37/39-45
RIDADR	UN 3265 8/PG 2
WGK Germany	3
Hazard Note	Corrosive
HS Code	29049090

MSDS Information

Provider	Language
SigmaAldrich	English

3-METHOXYBENZYL BROMIDE Usage And Synthesis

Chemical Properties	Colorless liquid
Uses	3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives. It may be used in the synthesis of the following: 6-(3-methoxyphenyl)-hexane-2,4-dione N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole
Uses	3-Methoxybenzyl bromide is a benzyl bromide derivative used as a benzyl group rearrangement catalyst.
General Description	3-Methoxybenzyl bromide is a benzyl bromide derivative.

3-METHOXYBENZYL BROMIDE Preparation Products And Raw materials

Raw materials	Ethyl acetate-->Diethyl ether-->PETROLEUM ETHER-->Sodium bicarbonate-->Carbon tetrachloride-->N-Bromosuccinimide-->Phosphorus tribromide-->tert-Butyl methyl ether-->3-Methylanisole-->m-Anisyl alcohol
Preparation Products	2-Bromo-5-methoxytoluene-->M-TyraMine HydrobroMide-->4-[(3-METHOXYBENZYL)OXY]BENZALDEHYDE-->CYCLOPROPYL 2-(3-METHOXYPHENYL)ETHYL KETONE-->1-(3-METHOXY-BENZYL)-1H-PYRAZOL-4-YLAMINE

3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE 4-FLUORO-3-METHOXYBENZYL BROMIDE 2-BROMO-5-METHOXYBENZYL BROMIDE 4-Methoxybenzyl bromide ,95%,4-METHOXYBENZYL BROMIDE 3-FLUORO-5-METHOXYBENZYL BROMIDE 2,3-DIBROMO-1-(2-NITROPHENYL)-3-(3,4,5-TRIMETHOXYPHENYL)PROPAN-1-ONE 3-(2-FLUOROPHENOXY)BENZYL BROMIDE 2,3,5,6-TETRAFLUORO-4-METHOXYBENZYL BROMIDE 97%,2,3,5,6-TETRAFLUORO-4-METHOXYBENZYL BROMIDE 5-BROMO-6-BROMOMETHYL-1,3-BENZODIOXOLE 7-BROMOMETHYL-4-METHYL-CHROMEN-2-ONE 3,5-BIS(BENZYLOXY)BENZYL BROMIDE BIS-3,4-DIMETHOXYSTILBENE DIBROMIDE 2,3-DIBROMO-3-(4-ETHOXY-3-METHOXYPHENYL)-1-(2-NITROPHENYL)PROPAN-1-ONE 3-(4-FLUOROPHENOXY)BENZYL BROMIDE 2-FLUORO-4-METHOXYBENZYL BROMIDE 3-BENZYLOXYBENZYL BROMIDE 4-[2-(3,4-DIMETHOXYPHENYL)-1,2-DIBROMOETHYL]-1,2-DIMETHOXYBENZENE 5-BROMOMETHYL-1,2,3-TRIMETHOXY-BENZENE

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