ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine

N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine

N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine Basic information
Product Name:N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine
Synonyms:1,4-Benzenediamine, N,N'-bis(1-methylpropyl)-;n,n’-di-s-butyl-p-phenylenediamine;N,N’-di-sec-butyl-benzene-1,4-diamine;n,n’-di-sec-butylparaphenylenediamine;n,n’-di-sec-butyl-p-phenyldiamine;n,n’-di-sec-butyl-p-phenylenediamin;n,n’-di-sek.butyl-p-fenylendiamin;N,N'-Bis(1-methylpropyl)-1,4-benzenediamine
CAS:101-96-2
MF:C14H24N2
MW:220.35
EINECS:202-992-2
Product Categories:Amines;C11 to C38;Nitrogen Compounds;efficiency antioxidant of gasoline
Mol File:101-96-2.mol
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine Structure
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine Chemical Properties
Melting point 17.8°C
Boiling point 159 °C / 7mmHg
density 0.942 g/mL at 20 °C(lit.)
vapor pressure 0.05Pa at 25℃
refractive index n20/D 1.539
Fp 100°C
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka8.67±0.50(Predicted)
form clear liquid
color Light yellow to Brown to Dark red
Water Solubility <0.1 g/100 mL at 20 ºC
BRN 2805827
Stability:Stable. Combustible.
LogP0.59-3.7 at 25℃
CAS DataBase Reference101-96-2(CAS DataBase Reference)
NIST Chemistry ReferenceN,N'-Di-sec-butyl-p-phenylenediamine(101-96-2)
EPA Substance Registry SystemN,N'-di-sec-Butyl-p-phenylenediamine (101-96-2)
Safety Information
Hazard Codes C,N,T
Risk Statements 25-34-43-50/53-41-38
Safety Statements 26-36/37/39-45-61-60
RIDADR UN 2922 8/PG 2
WGK Germany 3
RTECS SS9040000
F 10-23
HS Code 2921.51.5000
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data101-96-2(Hazardous Substances Data)
ToxicityLD50 oral in rat: 148mg/kg
MSDS Information
ProviderLanguage
N,N'-Di-sec-butyl-p-phenylenediamine English
SigmaAldrich English
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine Usage And Synthesis
Chemical Propertiesdark red liquid
UsesN,N''-di-sec-Butyl-p-phenylenediamine is used in method for preparing polyurethane adhesive.
General DescriptionAmber to red or dark reddish black liquid.
Air & Water ReactionsN,N'-Bis(1-methylpropyl)-1,4-phenylenediamine may be sensitive to prolonged exposure to air or light. Insoluble in water.
Reactivity ProfileN,N'-Bis(1-methylpropyl)-1,4-phenylenediamine reacts with oxidizing materials. [NTP,1992]. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Fire HazardN,N'-Bis(1-methylpropyl)-1,4-phenylenediamine is combustible.
Flammability and ExplosibilityNonflammable
Safety ProfilePoison by ingestion. Moderately toxic by inhalation and sh contact. Corrosive to skin. A mild allergen. Symptoms of exposure are sweating, flushmg, shortness of breath, and slow pulse. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine Preparation Products And Raw materials
4,4'-Thiobis(6-tert-butyl-m-cresol) Calcium bis[monoethyl(3,5-di-tert-butyl-4-hydroxylbenzyl)phosphonate] 2,3,5,6-TETRAMETHYL-1,4-PHENYLENEDIAMINE Buprofezin 2-sec-Butylphenol Antioxidant 168 tert-Butyl peroxyacetate Diethylene glycol monobutyl ether Butyl acrylate Butyl acetate p-Phenylenediamine dihydrochloride BUTYL OLEATE Butylated Hydroxytoluene Antioxidant 1010 N,N-Dimethyl-1,4-phenylenediamine 4-Aminodiphenylamine 2-Butoxyethanol p-Phenylenediamine
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