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(4S)-(-)-4-Isopropyl-2-oxazolidinone

(4S)-(-)-4-Isopropyl-2-oxazolidinone Basic information
Product Name:(4S)-(-)-4-Isopropyl-2-oxazolidinone
Synonyms:(4S)-4β-Isopropyloxazolidine-2-one;(S)-4-Isopropyloxazolidine-2-one;(S)-4β-Isopropyloxazolidine-2-one;4β-Isopropyloxazolidine-2-one;(4S)-(-)-4-Isopropyl-2-oxazolidinone,98%;(S)-4-isopropyl-2-1xazolidinone;(4S)-(-)-4-Isopropyl;(4S)-4-(Prop-2-yl)-1,3-oxazolidin-2-one
CAS:17016-83-0
MF:C6H11NO2
MW:129.16
EINECS:640-491-4
Product Categories:Chiral Reagents;Asymmetric Synthesis;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Peptide;Oxazolidinone;chiral;Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives
Mol File:17016-83-0.mol
(4S)-(-)-4-Isopropyl-2-oxazolidinone Structure
(4S)-(-)-4-Isopropyl-2-oxazolidinone Chemical Properties
Melting point 70-73 °C(lit.)
alpha -18 º (c=1, ethanol)
Boiling point 239.22°C (rough estimate)
density 1.1426 (rough estimate)
refractive index -17.5 ° (C=6, EtOH)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, Dichloromethane, Ethanol
pka12.72±0.40(Predicted)
form Crystalline Powder
color White
optical activity[α]20/D 18°, c = 6 in ethanol
Water Solubility Insoluble
BRN 3588198
CAS DataBase Reference17016-83-0(CAS DataBase Reference)
NIST Chemistry Reference(S)-(+)-4-isopropyl-2-oxazolidinone(17016-83-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
F 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
(4S)-(-)-4-Isopropyl-2-oxazolidinone Usage And Synthesis
Chemical PropertiesWhite to off-White Solid
UsesReagent employed as a chiral ligand in dirhodium(II) complexes and as a chiral auxiliary in aldol addition reactions. Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta.
Oxazolidinone (S)-(-)-4-(DIPHENYLMETHYL)-2-OXAZOLIDINONE (4s)-n-crotonyl-4-isopropyl-2-oxazolidinone,(S)-(+)-3-CROTONOYL-4-ISOPROPYL-2-OXAZOLIDINONE,(N-CROTONYL)-(4S)-ISOPROPYL-2-OXAZOLIDINONE telithromycin ISOPROPYL LAURATE (S)-(-)-5,5-DIPHENYL-4-(TERT-BUTYL)-2-OXAZOLIDINONE Cumene 3-Methyl-2-butanone (S)-(-)-4-tert-Butyloxazolidine-2,5-dione BOC-ILE-N-CARBOXYANHYDRIDE FMOC-ILE-N-CARBOXYANHYDRIDE N,N-Diisopropylethylamine (S)-(-)-4-ISOPROPYL-5,5-DIMETHYL-2-OXAZOLIDINONE Diisopropylamine (S)-4-(SEC-BUTYL)OXAZOLIDINE-2,5-DIONE (4S)-(-)-4-Isopropyl-2-oxazolidinone Isopropyl alcohol Cuminaldehyde Evans Reagent
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