Ethyl caprate

Ethyl caprate Basic information
Description References
Product Name:Ethyl caprate
Synonyms:Ethyl ester of Decanoic acid;RARECHEM AL BI 0168;N-DECANOIC ACID ETHYL ESTER;N-CAPRIC ACID ETHYL ESTER;Capric acid ethyl ester~Decanoic acid ethyl ester~Ethyl decanoate;FEMA 2432;ETHYL N-DECANOATE;ETHYL N-CAPRATE
CAS:110-38-3
MF:C12H24O2
MW:200.32
EINECS:203-761-9
Product Categories:Pharmaceutical Intermediates;110-38-3
Mol File:110-38-3.mol
Ethyl caprate Structure
Ethyl caprate Chemical Properties
Melting point -20°C
Boiling point 245 °C(lit.)
density 0.862 g/mL at 25 °C
vapor density 6.9 (vs air)
vapor pressure 1.8Pa at 20℃
refractive index n20/D 1.425
FEMA 2432 | ETHYL DECANOATE
Fp 216 °F
storage temp. Store below +30°C.
solubility H2O: insoluble
form Liquid
color Clear colorless
Odorat 100.00 %. sweet waxy fruity apple grape oily brandy
Odor Typewaxy
explosive limit0.7%(V)
Water Solubility insoluble
Merck 14,3776
JECFA Number35
BRN 1762128
LogP4.79
CAS DataBase Reference110-38-3(CAS DataBase Reference)
NIST Chemistry ReferenceDecanoic acid, ethyl ester(110-38-3)
EPA Substance Registry SystemEthyl decanoate (110-38-3)
Safety Information
Safety Statements 24/25
WGK Germany 2
RTECS HD9420000
TSCA Yes
HS Code 29159080
MSDS Information
ProviderLanguage
Ethyl caprate English
SigmaAldrich English
ACROS English
ALFA English
Ethyl caprate Usage And Synthesis
DescriptionEthyl caprate (also known as ethyl decanoate) is the ethyl ester form of caprate. It is a kind of product during the fermentation process of winemaking. It also exists in the essential oils of many kinds of natural fruits. It can be used as a common flavoring agent and food spices.
References[1]Langrand, G., et al. "Short chain flavour esters synthesis by microbial lipases." Biotechnology Letters 12.8 (1990): 581-586.
[2]Cakir, Ahmet. "Essential oil and fatty acid composition of the fruits of Hippophae rhamnoides L.(Sea Buckthorn) and Myrtus communis L. from Turkey." Biochemical Systematics and Ecology 32.9 (2004): 809-816.
[3]Takeoka, Gary R., Ron G. Buttery, and Robert A. Flath. "Volatile constituents of Asian pear (Pyrus serotina)." Journal of Agricultural and Food Chemistry40.10 (1992): 1925-1929.

Chemical PropertiesEthyl decanoate has a fruity odor reminiscent of grape (cognac). It has been also reported to have an oily, brandy-like odor.
Chemical Propertiesclear colourless liquid
OccurrenceReported found in cognac, apple, banana, cherry, citrus, grape, melon, pear, pinapple, and more.
Usesmanufacture of wine bouquets, cognac essence.
UsesEthyl Decanoate, is a fatty acid ester formed from capric acid and ethanol. It is a volatile ester produced during the fermentation in winemaking. It can also be used as a flavor and fragrance ingredients.
Definition ChEBI: Ethyl decanoate is a fatty acid ethyl ester of decanoic acid. It has a role as a metabolite. It is a fatty acid ethyl ester and a decanoate ester.
PreparationEthyl decanoate is prepared by esterification of decanoic acid and ethyl alcohol in the presence of HCl or H2SO4.
Aroma threshold valuesDetection: 8 to 12 ppb
Taste threshold valuesTaste characteristics at 20 ppm: waxy, fruity, sweet apple.
Synthesis Reference(s)The Journal of Organic Chemistry, 43, p. 371, 1978 DOI: 10.1021/jo00396a054
General DescriptionEthyl decanoate has ethereal, fruity, aromatic note that is considered to be essential for a fine wine flavor.
Safety ProfileA skin irritant. Combustible liquid when exposed to heat or flame; can react with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes. See ESTERS and ETHERS
LAURIC ANHYDRIDE ETHYL 10-BROMODECANOATE [(3S,9S,10R,13R,14S,17R)-10,13-Dimethyl-17-[(2R)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-yl] decanoate Span 60 Span 20 Ethyl pyruvate Cholesteryl palmitate RUBRATOXIN B Ascorbyl Palmitate Ethyl glyoxalate GAMMA-LINOLENIC ACID ETHYL ESTER Diethyl maleate Ethyl 2-acetyldecanoate Diethyl methylmalonate ISOXADIFEN-ETHYL Ethyl cinnamate CHOLESTERYL STEARATE Ethyl 3-oxodecanoate

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