ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic germanium TRIMETHYLGERMANIUM BROMIDE

TRIMETHYLGERMANIUM BROMIDE

TRIMETHYLGERMANIUM BROMIDE Basic information
Product Name:TRIMETHYLGERMANIUM BROMIDE
Synonyms:Germane, bromotrimethyl-;Trimethylgermane, bromo-;TRIMETHYLBROMOGERMANE;TRIMETHYLGERMANIUM BROMIDE;BROMOTRIMETHYLGERMANE;Trimethylgermanium bromide 98%;Trimethylgermyl bromide;Trimethylgermanium bromide, 98.6%
CAS:1066-37-1
MF:C3H9BrGe
MW:197.65
EINECS:213-913-6
Product Categories:Organogermanium;Organometallic Reagents;Others;organogermanium compound;Chemical Synthesis;Organometallic Reagents
Mol File:1066-37-1.mol
TRIMETHYLGERMANIUM BROMIDE Structure
TRIMETHYLGERMANIUM BROMIDE Chemical Properties
Melting point -25 °C (lit.)
Boiling point 114 °C (lit.)
density 1.54 g/mL at 25 °C (lit.)
refractive index n20/D 1.47(lit.)
Fp 99 °F
storage temp. Flammables area
form liquid
Specific Gravity1.54
color colorless
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Sensitive moisture sensitive
CAS DataBase Reference1066-37-1(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 10-34
Safety Statements 16-26-27-36/37/39-45
RIDADR UN 2920 8/PG 2
WGK Germany 3
TSCA No
HazardClass 3
PackingGroup II
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIMETHYLGERMANIUM BROMIDE Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesReagent for the formation of dienolates of α,β-unsaturated esters. Also useful for methylenecyclopentane annulation reactions.
UsesTrimethylgermanium bromide is a reagent for the formation of dienolates of α,β-unsaturated esters.1 Also useful for methylenecyclopentane annulation reactions.
TRIMETHYLGERMANIUM BROMIDE Preparation Products And Raw materials
Raw materialsBenzene, 1-(1-bromoethyl)-4-methyl-, (-)--->Tetramethylgermane-->4-Methylbenzyl bromide-->4-Bromobenzyl bromide-->4-Chlorobenzyl bromide-->Benzyl bromide
Preparation ProductsBENZYL PHENYL SULFIDE
GERMANIUM TETRABROMIDE TETRA-N-BUTYLGERMANE TRIPHENYLGERMANIUM CHLORIDE Tetramethylgermane TRIMETHYLGERMANIUM CHLORIDE DIMETHYLGERMANIUM DICHLORIDE TRIETHYLGERMANIUM CHLORIDE GERMANIUM (II) SULFIDE GERMANIUM TETRAIODIDE GERMANIUM(IV) ETHOXIDE TETRAETHYLGERMANE GERMANIUM CHLORIDE DIOXANE COMPLEX (1:1) Germanium oxide GERMANIUM(II) IODIDE DIETHYLGERMANIUM DICHLORIDE GERMANE Germanium TRIMETHYLGERMANE
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