(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Basic information
Product Name:(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
Synonyms:tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;(tert-Butoxycarbonylmethyl)tripheenyphosphonium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98 %;triphenyl tert butoxycarbonyl Methyl phosphoniuM broMide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide
CAS:59159-39-6
MF:C24H26BrO2P
MW:457.34
EINECS:
Product Categories:Olefination;Wittig Reagents;C-C Bond Formation
Mol File:59159-39-6.mol
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Structure
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Chemical Properties
Melting point 178 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol
form powder to crystal
color White to Almost white
BRN 4631405
CAS DataBase Reference59159-39-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29319019
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Usage And Synthesis
UsesReactant for:
  • Rhodium-catalyzed asymmetric hydrogenation reactions
  • Wittig reaction
  • Wittig methylenation
  • Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
  • Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
  • Wittig chain extension reactions
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Preparation Products And Raw materials
Preparation ProductsE-Caffeic acid-t-butyl ester
(Carbomethoxymethyl)triphenylphosphonium bromide Chlorodimethylphenylsilane Methyltriphenylphosphonium bromide Rocuronium bromide Sodium bromide Tetrabutylammonium bromide CARBOXYMETHYL DIPHENYLPHOSPHINE OXIDE (2-HYDROXYETHYL)TRIPHENYLPHOSPHONIUM BROMIDE Methylmagnesium Bromide tert-Butanol (ETHOXYCARBONYLMETHYL)DIPHENYLPHOSPHINE Sodium bromate Tetrabutyl titanate Ethidium bromide Allyl bromide (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide (Carbethoxymethyl)triphenylphosphonium bromide Methyl bromide

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