FORMANILIDE

FORMANILIDE Basic information
Product Name:FORMANILIDE
Synonyms:n-formyl-anilin;n-formylaniline;N-Phenyleormamide;n-phenyl-formamid;ForManilide, 99+% 100GR;Formanilide, 99+%;(Phenylamino)formaldehyde;Anilinoformaldehyde
CAS:103-70-8
MF:C7H7NO
MW:121.14
EINECS:203-136-0
Product Categories:Amides;Building Blocks;C2 to C7;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:103-70-8.mol
FORMANILIDE Structure
FORMANILIDE Chemical Properties
Melting point 46-48 °C(lit.)
Boiling point 166 °C14 mm Hg(lit.)
density 1.144 g/mL at 25 °C(lit.)
refractive index 1.5908 (estimate)
Fp >230 °F
storage temp. Sealed in dry,2-8°C
solubility water: soluble25.4g/L at 20°C
form Crystals
pka15.00±0.70(Predicted)
Specific Gravity1.144
color White to pale grayish-beige
Merck 14,4238
BRN 906934
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference103-70-8(CAS DataBase Reference)
EPA Substance Registry SystemFormanilide (103-70-8)
Safety Information
Risk Statements 22
Safety Statements 22-24/25
WGK Germany 2
RTECS BY1780000
8
TSCA Yes
HS Code 29242990
Hazardous Substances Data103-70-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
FORMANILIDE Usage And Synthesis
Chemical Propertieswhite or light yellow crystals or powder
UsesFormanilide was used to study the zero electron kinetic energy(ZEKE) spectra of cis- and trans-formanilide. It was used to investigate the gas-phase structures of the two isomers of the trans-formanilide-water complex by two-colour (1+1′) resonance enhanced multiphoton ionisation (REMPI) and ZEKE spectroscopy.
DefinitionChEBI: A member of the class of formamides that is formamide in which one of the amino hydrogens is replaced by a phenyl group.
Synthesis Reference(s)Synthetic Communications, 13, p. 635, 1983 DOI: 10.1080/00397918308060342
Tetrahedron Letters, 26, p. 3703, 1985 DOI: 10.1016/S0040-4039(00)89228-X
General DescriptionWhite crystalline solid.
Air & Water ReactionsFORMANILIDE may be sensitive to prolonged exposure to air. . Soluble in water.
Reactivity ProfileFORMANILIDE is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Health HazardSYMPTOMS: Exposure to FORMANILIDE may cause cyanosis, headache, dizziness, confusion, decreased blood pressure, convulsions and coma.
Fire HazardFORMANILIDE is probably combustible.
Purification MethodsCrystallise formanilide from Et2O (m 45.3o), Et2O/pet ether (m 46o), pet ether (m 47.6o), ligroin/xylene, or distil it preferably under reduced pressure. [Beilstein 12 H 230, 12 II 135, 12 III 453.]
FORMANILIDE Preparation Products And Raw materials
Preparation Products4-Aminobenzotrifluoride-->4-Aminodiphenylamine-->N-Methylformanilide-->phthalogen auxiliary BSK-->phthalogen auxiliary agent BSM-->(2,4-dichlorophenyl)imidocarbonyl dichloride-->Methoxymethyldiphenylamine-->PHENYL ISOCYANIDE DICHLORIDE-->N-BOC ANILINE-->ETHYL N-PHENYLFORMIMIDATE-->3-Methoxydiphenylamine-->4-Hydroxy-2,6-dimethoxybenzaldehyde-->Quinazoline-->Benzenesulfonyl chloride, 4-(formylamino)-
2-Chloro-N-(2,6-dimethylphenyl)acetamide 4'-Chloroacetoacetanilide N-METHYL-N-PHENYLCARBAMOYL CHLORIDE 4-ACETAMIDOBENZONITRILE 2-BENZOYLACETANILIDE Acetaminophen ACID BLUE 41 BENZANILIDE 4'-CHLOROACETANILIDE N-Acetylanthranilic acid 2-Chloro-N-[4-chloro-2-(2-chlorobenzoyl)phenyl]acetamide N-(4-CHLORO-PHENYL)-OXALAMIC ACID ETHYL ESTER 1-(2-hydroxyethyl)-3-phenylurea 2'-Fluoroacetanilide 3-(TRIFLUOROMETHYL)ACETANILIDE 1-CARBOXYETHYL N-PHENYLCARBAMATE 2-acetamido-3-nitro-9-fluorenone 2-ACETAMIDOFLUORENE

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