TRIMETHYLTHIOUREA

TRIMETHYLTHIOUREA Basic information
Product Name:TRIMETHYLTHIOUREA
Synonyms:1,1,3-trimethyl-2-thio-ure;1,1,3-Trimethyl-2-thiourea;1,1,3-trimethyl-2-thiourea[qr];1,1,3-Trimethylthiourea;thiourea,trimethyl-[qr];trimethyl-thioure;Urea, 1,1,3-trimethyl-2-thio-;urea,1,1,3-trimethyl-2-thio-[qr]
CAS:2489-77-2
MF:C4H10N2S
MW:118.2
EINECS:219-644-0
Product Categories:
Mol File:2489-77-2.mol
TRIMETHYLTHIOUREA Structure
TRIMETHYLTHIOUREA Chemical Properties
Melting point 84°C
Boiling point 221.2°C
density 1.027 (estimate)
refractive index 1.5000 (estimate)
form solid
pka15.29±0.70(Predicted)
color White to Almost white
CAS DataBase Reference2489-77-2(CAS DataBase Reference)
EPA Substance Registry SystemTrimethylthiourea (2489-77-2)
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
RTECS YU4900000
HS Code 2930.90.9250
Hazardous Substances Data2489-77-2(Hazardous Substances Data)
MSDS Information
TRIMETHYLTHIOUREA Usage And Synthesis
DescriptionTrimethylthiourea is a thiourea derivative. Patients sensitized to ethylbutyl thiourea ean also react to trimethylthiourea.
Uses1,1,3-Trimethylthiourea can be used to synthesize many isothiouronium compounds.
General DescriptionPrisms (from benzene or ligroin) or off-white powder.
Air & Water ReactionsVery slightly soluble in water.
Reactivity ProfileAn organosulfide amide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Health HazardACUTE/CHRONIC HAZARDS: When heated to decomposition TRIMETHYLTHIOUREA emits toxic fumes of nitrogen oxides and sulfur oxides.
Fire HazardFlash point data for TRIMETHYLTHIOUREA are not available; however, TRIMETHYLTHIOUREA is probably combustible.
Contact allergensTrimethylthiourea is a thiourea derivative used, for example, for polychloroprene (neoprene) rubber vul- canization. Patients sensitized to ethylbutyl thiourea can also react to trimethylthiourea.
Safety ProfilePoison by ingestion. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also ISOTHIOUREA.
TRIMETHYLTHIOUREA Preparation Products And Raw materials
1-ACETYL-2-THIOHYDANTOIN 3-PHENYL-2-THIOXO-1,2,3,4-TETRAHYDROQUINAZOLIN-4-ONE Tetramethylthiourea TIMTEC-BB SBB000615 PHENYLTHIOHYDANTOIN-TRYPTOPHAN PTH-TYROSINE 1,1-DIMETHYL-3-(META-TOLYL)-2-THIOUREA PHENYLTHIOHYDANTOIN-DL-ALANINE 5-METHYL-2-THIOURIDINE PTH-L-PHENYLALANINE TIMTEC-BB SBB000597 PTH-SERINE 1,3-DIETHYL-2-THIOBARBITURIC ACID DIMETHYLPHENYLTHIOUREA MEROCYANINE 540 1-(2-Hydroxyethyl)imidazolidine-2-thione MTH-GLYCINE PTH-GLYCINE

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