1,8-DIAMINO-P-MENTHANE

1,8-DIAMINO-P-MENTHANE Basic information
Product Name:1,8-DIAMINO-P-MENTHANE
Synonyms:4-(1-Amino-1-methylethyl)-1-methylcyclohexanamine;4-amino-.alpha.,.alpha.-4-trimethyl-Cyclohexanemethanamine;4-Amino-alpha,alpha,4-trimethylcyclohexanemethamine;4-amino-alpha,alpha,4-trimethyl-cyclohexanemethanamin;ai3-23799;Menthanediamine;nsc5612;p-Menthane-1,8-diamine
CAS:80-52-4
MF:C10H22N2
MW:170.3
EINECS:201-287-7
Product Categories:Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Polyamines
Mol File:80-52-4.mol
1,8-DIAMINO-P-MENTHANE Structure
1,8-DIAMINO-P-MENTHANE Chemical Properties
Melting point −45 °C(lit.)
Boiling point 107-126 °C10 mm Hg(lit.)
density 0.914 g/mL at 25 °C(lit.)
vapor pressure 10 mm Hg ( 20 °C)
refractive index n20/D 1.4805(lit.)
Fp 200 °F
storage temp. 2-8°C
pka11.02±0.70(Predicted)
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference80-52-4(CAS DataBase Reference)
EPA Substance Registry Systemp-Menthane-1,8-diamine (80-52-4)
Safety Information
Hazard Codes T
Risk Statements 23/24/25-34
Safety Statements 26-27-28-36/37/39-45
RIDADR UN 2922 8/PG 2
WGK Germany 3
RTECS OS8925000
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
1,8-DIAMINO-P-MENTHANE Usage And Synthesis
Chemical Propertiesdark coloured liquid
UsesCuring agent for epoxy resins, chemical intermediate.
Uses1,8-Diamino-p-menthane is generally used in the synthesis of various Schiff bases that are used in the preparation of coordination complexes with Cu(II), Zn(II), Cr(III), Fe(III) and Co(III) ions. It is also used as a precursor to synthesize heterocyclic Schiff base derivatives with herbicidal activity.
DefinitionA primary alicyclic diamine, also a tert-alkylamine.
General DescriptionBlackish liquid.
Air & Water ReactionsSlightly water soluble .
Reactivity Profile1,8-DIAMINO-P-MENTHANE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
HazardStrong irritant to eyes and skin, calls for eye protection.
Fire Hazard1,8-DIAMINO-P-MENTHANE is combustible.
1,8-DIAMINO-P-MENTHANE Preparation Products And Raw materials
(S)-(-)-2-METHYLBUTYLAMINE Amylamine 2,5-DIMETHYLHEPTANE TERT-AMYLAMINE (R)-2-AMINO-6-METHYLHEPTANE, 98% E.E., 95 2,6-DIMETHYLOCTANE (R)-2-Aminooctane (±)-Pindobind, N1-Bromoacetyl-N8-3μ-(4-indolyloxy)-2μ-hydroxy-propyl-[Z]-1,8-diamino-p-menthane (S)-(+)-2-Amino-3-methylbutane TRANS-1-ISOPROPYL-4-METHYLCYCLOHEXANE 2-Ethylbutylamine Cyclohexylamine 1,8-DIAMINO-P-MENTHANE 1,5-Dimethylhexylamine (S)-(+)-1-Cyclohexylethylamine (R)-(-)-2-Aminobutane Isopropylamine Ethylcyclohexane

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