Clove oil

Clove oil Basic information
Description References
Product Name:Clove oil
Synonyms:oils,cloveleaf;oils,clovestem;eugenia oil;EUGENIA CARYOPHYLLUS (CLOVE) LEAF OIL;CLOVE OIL;OIL OF CLOVE;CLOVE BUD OIL FCC;OIL OF CLOVES, FOR MICROSCOPY
CAS:8000-34-8
MF:C7H12ClN3O2
MW:205.64208
EINECS:616-772-2
Product Categories:Essential oil
Mol File:8000-34-8.mol
Clove oil Structure
Clove oil Chemical Properties
Boiling point 251 °C(lit.)
density 1.05 g/mL at 25 °C
refractive index n20/D 1.532(lit.)
FEMA 2323 | CLOVE BUD OIL (EUGENIA SPP.)
Fp >230 °F
form Liquid
color Yellow
Odorat 100.00 %. spicy aromatic woody balsamic minty peppery phenolic powdery
Odor Typespicy
optical activity[α]20/D 1.50 to 0.0°, neat
Water Solubility Insoluble in water
Merck 13,2443
Stability:Stable. Probably combustible.
EPA Substance Registry SystemClove oil (8000-34-8)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 36/37/38-21/22
Safety Statements 26-36
WGK Germany 3
RTECS GF6900000
MSDS Information
ProviderLanguage
Clove oil English
SigmaAldrich English
Clove oil Usage And Synthesis
DescriptionThe clove oil is a kind of essential oil extracted from the clove plants, Syzygium aromaticum. It is divided into three categories including bud oil, leaf oil and stem oil. Clove oil has many applications such as relieving toothache, anesthetizing or euthanizing laboratory or pet fish. It has also shown that clove oil has many health effects. For example, it has strong anti-inflammatory effect, and can protect the liver against disease. It can also be used as an antiseptic for oral infection and a broad-spectrum antimicrobial reagent. Clove oil can generally support the health of our liver, skin, hair and mouth.
clove oil
Referenceshttps://draxe.com/clove-oil-uses-benefits/
https://en.wikipedia.org/wiki/Oil_of_clove
Chemical PropertiesClove bud oil is obtained in 15–20% yield by steam distillation of the dried flower buds. Clove bud oil, similar to the leaf oil, is a yellow to brown, sometimes slightly viscous liquid. It turns dark purple-brown on contactwith iron. The oil has the spicy odor and flavor that are characteristic of eugenol. d2020 1.042–1.063; n20D 1.5280–1.5380; α20D ?1.5 ° to 0 °; phenol content: 85–93%; content by GC: eugenol 75–85%, caryophyllene 2–7%, eugenol acetate 8–15%.
Chemical PropertiesClove bud oil is obtained by the distillation of buds with water or steam. The yield is typically between 15 and 18%, but is dependent on the quality of the buds, precautions exercised and distiller efficiency. Of the clove oils, clove bud oil is the most expensive. Approximately 50 tons is produced each year in Madagascar. The oil has the characteristic clove-like aroma and a burning, spicy flavor.
Physical propertiesThe oil is clear and mobile. The color usually darkens with age.
OccurrenceFound in the buds of Eugenia caryophyllata Thunb. (Fam. Myrtaceae) (Fenarolfs Handbook of Flavor Ingredients, 1971).
UsesClove oil is an essential oil used in tooth powder, confectionery, microscopy; local anesthetic for toothaches; some perfumery uses(honeysuckle; rose; balsam; aftershave fragrances; herbal)
Usesclove bud oil has similar properties to clove oil, though it is most often used for its odor-masking properties. Distillates from dried buds are considered of higher quality than those obtained from the stems and leaves. Clove oil derived from the plant’s leaves is sometimes used to adulterate the oil obtained from the bud.
UsesClove oil, the traditional cure for toothache, can do more than numb the gums. This sweet, warm, spicy oil is an effective antiseptic that can be applied to infected wounds; in fact, when diluted to 1 percent, clove oil is up to four times more effective than phenol in killing bacteria. An effective insect repellent, clove oil can be used on herbal flea collars or added to herbal sprays. Taken internally, it helps prevent flatulence, digestive problems and diarrhea. As clove oil was traditionally recommended for strengthening the uterus and aiding in childbirth (some authorities recommend that women eat cloves during their last month of pregnancy and drink clove tea during labor), this essential oil may be helpful to dogs and cats in the week before giving birth. Clove oil is also an effective vermifuge or worm killer.
Three types of clove oil are available: clove bud, clove leaf and clove stem. All three can cause skin and mucous membrane irritation and should be greatly diluted when used topically. Clove bud oil has the lowest eugenol percentage and is the least toxic. All of the clove oils are safe for internal consumption and are widely used flavoring agents.
Like cinnamon, cloves can be added to a pet's food. Use freshly ground cloves for this purpose because the spice's essential oils deteriorate rapidly after grinding. This is why freshly ground cloves smell so different from ground cloves that have been sitting on a shelf for months. The essential oils in whole cloves will dull the plastic parts of your spice grinder (clean it immediately after use with soap and water) and if you fill vegetarian gelatin capsules (Vegicaps) with ground cloves, their essential oil will cause the capsules to shatter within a few days. Regular gelatin capsules will not break.

DefinitionExtractives and their physically modified derivatives. Eugenia caryophyllata or Caryophyllus aromaticus, Myrtaceae.
PreparationBy water distillation of the buds of E. caryophyllata Thunb. (Fenarolfs Handbook of Flavor Ingredients, 1971).
Essential oil compositionClove bud oil contains 70 to 90% eugenol, 2 to 17% eugenyl acetate, 5 to 12% α- and β-caryophyllene and traces of caryophyllene epoxide, gallic acid, flavonoids, oleanolic acid, rhamnetin, methyl salicylate, methyl-n-amyl ketone, methyln- heptyl ketone, methyl-n-amyl carbinol, methyl-n-heptyl carbinol, methyl alchohol, methyl benzoate, furfural, α-methyl furfural, furfuryl alchohol, vanillin and possibly β-pinene, valeraldehyde, methyl furfuryl alcohol and dimethyl furfural.*
Toxicity evaluationThe acute oral LD50 value in rats was reported as 2*65 g/kg (2.18-3.12 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as approximately 5 g/kg (Moreno, 1973). The acute oral LD50 of clove oil for rats was found to be 372 mg/100-g rat (von Skramlik, 1959). Clove oil was toxic to mice when applied to the skin in two doses 7 days apart (Roe & Field, 1965).
Clove oil Preparation Products And Raw materials
Raw materialsEugenol
Preparation ProductsBenzyl alcohol-->Eugenol-->Methyl salicylate-->Linalyl acetate-->2-Heptanone-->CLOVE STEM OIL-->EUGENIA CARYOPHYLLUS (CLOVE) LEAF OIL
Clove Oil Rectified 85% METHYL ISOCYANOACETATE TerpenesandTerpenoids,clove-oil Terpenes and terpenoids, clove-oil, reaction products with formaldehyde Tris(2,4-pentanedionato)chroMiuM(III) DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) SALCOMINE 2,4-PENTANEDIONE, SILVER DERIVATIVE EUGENOL ACETATE Tosylmethyl isocyanide CLOVE OIL B.P COBALT(II) ACETYLACETONATE Cupric acetylacetonate TERT-BUTYL ISOCYANIDE 1-Benzyloxy-2-methoxy-4-propenylbenzene Famoxadone Ferric acetylacetonate COBALT ETHYLENE DIAMINE CHLORIDE Oil Of Cloves

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