Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct

Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct Basic information
Appearance Uses
Product Name:Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct
Synonyms:Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct, Min. 98%;Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(tricyclohexylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [PCy3 Palladacycle Gen. 3];Methanesulfonato(tricyclohexylphosphine)(2'-amino-1,1'-biphe...;PCy3 Pd G3 / Methanesulfonato(tricyclohexylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(tricyclohexylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct,[PCy3 Palladacycle Gen. 3];Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct;Methanesulfonato(tricyclohexylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / PCy3 Pd G3
CAS:1445086-12-3
MF:C31H46NO3PPdS
MW:650.16
EINECS:
Product Categories:Buchwald Ligands&Precatalysts;Buchwald Precatalysts Series;Pd
Mol File:1445086-12-3.mol
Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct Structure
Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct Chemical Properties
Melting point 219-224 °C (decomposition)
form Powder
color off-white to beige
Safety Information
MSDS Information
Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct Usage And Synthesis
Appearanceoff-white to beige powder
UsesA new palladium precatalyst for C-C and C-N cross-coupling reactions.
Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct Preparation Products And Raw materials
Raw materials2-Aminobiphenyl-->(2'-AMino-1,1'-biphenyl-2-yl)MethanesulfonatopalladiuM(II) diMer-->Tricyclohexyl phosphine
RuPhos Pd G3 XPhos Pd G1 tBuXPhos Pd G1 RuPhos Pd G2 SPhos Pd G1, Methyl t-Butyl Ether Adduct t-BuBrettPhos Palladacycle Gen. 3 RuPhos Palladacycle Gen. 4 Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) t-BuXphos Palladacycle Gen. 4 Palladacycle Gen. 3 BrettPhosPalladacycle SPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct XPhos Pd G2 BrettPhos Pd G3 Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) cataCXium A-Pd-G2 tBuXPhos-Pd-G3

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