4-Acetylphenylboronic acid

4-Acetylphenylboronic acid Basic information

Product Name:	4-Acetylphenylboronic acid
Synonyms:	RARECHEM AH PB 0162;P-ACETYLPHENYLBORONIC ACID;TIMTEC-BB SBB000146;4-ACETYLPHENYLBORONIC ACID;4-ACETYLBENZENEBORONIC ACID;ACETOPHENONE-4-BORONIC ACID;AKOS BRN-0001;Boronic acid, (4-acetylphenyl)- (9CI)
CAS:	149104-90-5
MF:	C8H9BO3
MW:	163.97
EINECS:	629-086-3
Product Categories:	Boronate Ester;Potassium Trifluoroborate;Boronic Acids;Boronic Acids and Derivatives;B (Classes of Boron Compounds);Boronic Acids;Organoborons;ACETYLGROUP;blocks;BoronicAcids;Boronic Acid series;Boronic Acid;Acetyl;Aryl;bc0001
Mol File:	149104-90-5.mol

4-Acetylphenylboronic acid Chemical Properties

Melting point	240-244 °C(lit.)
Boiling point	354.2±44.0 °C(Predicted)
density	1.19±0.1 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	DMSO (Slightly), Methanol (Slightly)
form	Crystalline Powder
pka	7.58±0.10(Predicted)
color	Pale yellow to yellow
Water Solubility	25 g/L
BRN	7869162
CAS DataBase Reference	149104-90-5(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36-37/39
WGK Germany	3
Hazard Note	Irritant/Keep Cold
HazardClass	IRRITANT
HS Code	29310095

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

4-Acetylphenylboronic acid Usage And Synthesis

Chemical Properties	white to light yellow crystal powder
Uses	4-Acetylphenylboronic acid4-Acetylphenylboronic Acid is used in several metal catalyzed cross-coupling reaction studies.
Uses	Reactant involved in: Palladium-catalyzed decarboxylative coupling Copper-catalyzed hydroxylation Palladium-catalyzed Suzuki-Miyaura cross-coupling Cross-coupling with α-bromocarbonyl compounds Oxidation catalyzed by Baeyer-Villiger monooxygenases 1,5-substitution reactions
Uses	suzuki reaction
General Description	4-Acetylphenylboronic acid is a boronate, belongs to a class of synthetic organic compounds. It reacts rapidly with peroxynitrite (ONOO(-)) to form stable hydroxy derivatives. It undergoes Suzuki coupling with 4-bromotriphenylamine catalyzed by dichlorobis(triphenylphosphine)Pd(II), during the synthesis of dendrimers.

4-Acetylphenylboronic acid Preparation Products And Raw materials

Raw materials	Tetrahydrofuran-->n-Butyllithium-->p-Toluenesulfonic acid-->Triethyl orthoformate-->Triisopropyl borate-->4'-Bromoacetophenone
Preparation Products	(4-ACETYLPHENYL)PHENYLMETHANE-->4'-(IMIDAZOL-1-YL)ACETOPHENONE-->ETHYL 4-ACETYLBENZOATE-->1-(4-(OXETAN-3-YL)PHENYL)ETHANONE-->1-(4-(1,4-dioxa-8-azaspiro[4.5]decan-8-yl)phenyl)ethanone-->CHEMBRDG-BB 4015547

4-BROMOTHIOPHENE-3-CARBOXYLIC ACID 3-DIISOPROPYLAMINO-1,2-PROPANEDIOL 4-Tolylboronic acid N,N-DIISOPROPYL-2-[[6-(METHYLSULPHONYL)INDOL-1-YL]OXY]ACETAMIDE N-ACETYL-L-TYROSINE ETHYL ESTER 1-(2,6-dimethylpiperidin-1-yl)-3-(methylamino)propan-2-ol 5-BUTYL-5-ETHYL-N,N,N',N'-TETRACYCLOHEXYL-3,7-DIOXAAZELAIC DIAMIDE 2-DIISOPROPYLAMINOETHYL METHACRYLATE 3-ACETYLPHENYLBORONIC ACID, PINACOL ESTER LITHIUM IONOPHORE VIII PANGAMIC ACID AKOS BC-3100 Phenylboronic acid 4-Hydroxyphenylboronic acid DIISOPROPYLAMINOACETALDEHYDE DIETHYL ACETAL 3-Acetamidophenylboronic acid 4-Acetylphenylboronic acid 2-FLUORO-5-ACETYLPHENYLBORONIC ACID

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