METHYL ABIETATE

METHYL ABIETATE Basic information
Product Name:METHYL ABIETATE
Synonyms:ABALYN;METHYL ABIETATE;METHYL ESTER OF ROSIN;1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-,methylester,[1R-(1.alpha.,1-Phenanthrenecarboxylicacid;(1R)-1,2,3,4,4a,4bα,5,6,10,10aα-Decahydro-1,4aβ-dimethyl-7-(1-methylethyl)-1-phenanthrenecarboxylic acid methyl ester;(1R)-1,2,3,4,4a,4bα,5,6,10,10aα-Decahydro-1,4aβ-dimethyl-7-(1-methylethyl)-1α-phenanthrenecarboxylic acid methyl ester;13-Isopropylpodocarpa-7,13-dien-18-oic acid methyl ester;Abietic acid methyl
CAS:127-25-3
MF:C21H32O2
MW:316.48
EINECS:204-832-7
Product Categories:
Mol File:127-25-3.mol
METHYL ABIETATE Structure
METHYL ABIETATE Chemical Properties
Melting point <25 °C
Boiling point bp 360-365° with decompn
density d2020 1.040
vapor pressure 0.009Pa at 25℃
refractive index nD20 1.530
Fp 180-218°C
storage temp. Refrigerator
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
color Methyl abietate is a colourless to yellow, almost odourless, thick liquid
Water Solubility 17μg/L at 25℃
LogP6.75 at 25℃
EPA Substance Registry SystemMethyl abietate (127-25-3)
Safety Information
toxicityBoth the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1972)
MSDS Information
METHYL ABIETATE Usage And Synthesis
Chemical PropertiesPale Yellow Thick Oil
OccurrenceWood rosin is found in the resinous residue of turpentine (Arctander, 1960)
UsesMethyl Abietate was used as an antiplasticizer for polycarbonates.
UsesAs a solvent for ester gums, rosin, many synthetic resins, ethyl cellulose, rubber, etc.; in the manufacture of varnish resins; as ingredient in adhesives.
PreparationPrepared by esterification of wood rosin with methanol.
Flammability and ExplosibilityNotclassified
Safety ProfileLow toxicity by ingestion and skin contact. A skin irritant. Probably slightly toxic. Combustible liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
METHYL ABIETATE Preparation Products And Raw materials
Raw materialsRosin-->Abieticanhydride-->ABIETIC ACID SODIUM SALT-->ABIETIC ACID-->Methanol-->Dimethyl sulfone-->Dimethyl sulfate-->Iodomethane-->Dimethyl carbonate
11-METHYLDODECANOIC ACID 7-OCTENOIC ACID METHYL 2-METHYLOCTANOATE METHYL 7-METHYLOCTANOATE ABIETIC ACID ETHYL ESTER 3-METHYL-1-CYCLOHEXANECARBOXYLIC ACID 4,4-DIMETHYLHEXANOIC ACID 2,2-DIMETHYL-6-HEPTENOIC ACID METHYL 10-UNDECENOATE CIS-5-DODECENOIC ACID Z-9-TETRADECENAL METHYL 6-METHYLOCTANOATE METHYL 5-METHYLHEXANOATE PENTAERYTHRITOL ABIETATE DIETHYLENE GLYCOL ABIETATE 2,2-DIMETHYLHEPTANOIC ACID 5-HEXENOIC ACID METHYL ESTER METHYL UNDECYLENATE

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