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| | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Basic information |
| Product Name: | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE | | Synonyms: | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;Iridium(1+), (1,2,5,6-.eta.)-1,5-cyclooctadienebis(methyldiphenylphosphine)-, hexafluorophosphate(1-);methyl(diphenyl)phosphane;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97% | | CAS: | 38465-86-0 | | MF: | C34H38F6IrP3 | | MW: | 845.79 | | EINECS: | | | Product Categories: | Ir;Catalysis and Inorganic Chemistry;Chemical Synthesis;Iridium | | Mol File: | 38465-86-0.mol |  |
| | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties |
| Melting point | 224 °C (dec.) (lit.) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Crystalline Powder | | color | Red | | Water Solubility | Soluble in acetone. Insoluble in water. | | Sensitive | Air & Moisture Sensitive |
| | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Usage And Synthesis |
| Chemical Properties | red crystalline powder | | Uses | (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates. |
| | (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials |
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