6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol

6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol Basic information
Product Name:6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol
Synonyms:6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol;Prometaphanine;Hasubanan-8-ol, 6,7-didehydro-8,10-epoxy-3,4,7-trimethoxy-17-methyl-, (8β,10β)- (9CI);(10β)-10-Hydroxy-3,4,7-trimethoxy-17-methyl-6,7-didehydrohasubanan-8-one
CAS:6858-85-1
MF:C20H25NO5
MW:359.42
EINECS:
Product Categories:
Mol File:6858-85-1.mol
6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol Structure
6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol Chemical Properties
Boiling point 544.4±50.0 °C(Predicted)
density 1.35±0.1 g/cm3(Predicted)
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form Powder
pka12.33±0.40(Predicted)
Safety Information
MSDS Information
6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol Usage And Synthesis
DescriptionThis amorphous alkaloid from Stephania japonica Miers is almost a tautomeric mixture. It yields a crystalline methiodide, m.p. 207°C; [α]20D - 32° (MeOH) which may be used to characterize the base. Three methoxy1 groups, one hydroxyl group and a methylimino group are present in the molecule. When heated with AC20 at 180°C in a sealed tube, the base gives 1-acetoxy-2:S:6- trimethoxyphenanthrene, m.p. 140°C.
ReferencesTomita, Ibuka, Inubushi., Tetrahedron Lett., 3617 (1964)
Tomita, Inubushi, Ibuka., J. Pharm. Soc., Japan, 87, 381 (1967)
6,7-Didehydro-8β,10β-epoxy-3,4,7-trimethoxy-17-methylhasubanan-8-ol Preparation Products And Raw materials
2-(3,4-Dihydroxyphenyl)-8-(2-O-beta-L-galactopyranosyl-beta-D-glucopyranosyl)-5,7-dihydroxy-4H-1-Benzopyran-4-one Hydroxyecdysone (4E,6E)-1,7-Diphenyl-4,6-heptadien-3-one Artemether beta-Sitosterol hydroxygenkwanin Perivine alpha-Terpineol beta-Eudesmol MOSLOFLAVONE (-)-Huperzine A alpha-Cyperone

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