MULLITE

MULLITE Basic information
Product Name:MULLITE
Synonyms:mullite(al6o5(sio4)2);MULLIT;MULLITE;ALUMINUM OXIDE-SILICON OXIDE;ALUMINUM SILICATE, POWDER;92700, MULLITE (LATTICE SPACING, OTHER P;MULLITE, LATTICE SPACING AND OTHER PARAMETERS(CRM STANDARD);REFRACTORYMULLITEFIBRE
CAS:1302-93-8
MF:Al6O13Si2
MW:426.05
EINECS:215-113-2
Product Categories:Inorganics
Mol File:1302-93-8.mol
MULLITE Structure
MULLITE Chemical Properties
Melting point 1750℃ [JAN85]
density 3.16 g/cm3
form powder
color White
Water Solubility Insoluble in water.
Exposure limitsACGIH: TWA 1 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
EPA Substance Registry SystemMullite (Al6O5(SiO4)2) (1302-93-8)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
RTECS BD1450000
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
MULLITE Usage And Synthesis
Chemical Propertiescolorless; rhomb, a=0.7557nm, b=0.76876 nm, c=0.28842 nm; hardness: hot pressed 13.6GPa, sintered 12.7GPa; indentation microfracture 2.02MPa ·m1/2; submicrometer powder(s) can be prepared by hydrolysis of mixed alkoxides, followed by drying and calcining up to 1600°C; sinter, microstructure [SOM91]; phases equilibria in mullite [PAS88]; other data in [HIR89] [ROB67] [MIZ89]
UsesMullite is present in the form of needles in porcelain, it is used in high-mullite based products is in hot blast stove checker bricks, melting and firing processes, and is used as a refractory material, manufacture of a type of crucible, steel industry, electronic substrates and protective coatings.
Industrial usesArtificial mullite, or synthetic mullite, a ceramic material made by a prolonged fusing in the electric furnace of a mixture of silica sand or diasphoric clay and bauxite, has the composition 3Al2O3·2SiO2, has a melting point of 1810 C, and softens at 1650 C.
Mullite occurs in nearly all ceramic products containing alumina and silica but, with the exception of refractories, is seldom introduced as such except as calcined kyanite.
The bricks are resistant to flame and to molten ash, and have a low, uniform coefficient of thermal expansion and a heat conductivity only slightly above that of fireclays. Normally, mullite has very fine crystals that change form and become enlarged after prolonged heating, making the product porous and permeable. For stable high-temperature refractories the mullite is prefused to produce larger crystals. At very high temperatures mullite tends to decompose to form corundum and alkali-silicate minerals of lower heat resistance. Mullite is also used for making spark plugs, chemical crucibles, and extruding dies, and a foamed mullite is used as a uniformly latticed honeycomb structure for lightweight, heat-resistant structural parts.

MULLITE Preparation Products And Raw materials
KAOLIN Boehmite BAUXITE Aluminum oxide LICHROSORB(R) RP8 ALUMINUM SILICON Aluminum kyanite SILICA ALUMINUM SILICATE MULLITE MULLITE 325 MESH

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