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| | (19Z)-Anhydrovobasinediol Basic information |
| Product Name: | (19Z)-Anhydrovobasinediol | | Synonyms: | (19Z)-Anhydrovobasinediol;3β,17-Epoxyvobasan;Anhydrovobasinediol;Taberpsychine;Taberpsychin;Vobasan, 3,17-epoxy-, (3β)- | | CAS: | 19452-84-7 | | MF: | C20H24N2O | | MW: | 308.41736 | | EINECS: | | | Product Categories: | | | Mol File: | 19452-84-7.mol |  |
| | (19Z)-Anhydrovobasinediol Chemical Properties |
| Melting point | 20So C (dec.). | | Boiling point | 490.6±45.0 °C(Predicted) | | density | 1.213±0.06 g/cm3(Predicted) | | solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. | | form | Powder | | pka | 17.39±0.20(Predicted) |
| | (19Z)-Anhydrovobasinediol Usage And Synthesis |
| Description | An alkaloid which occurs in Tabernaemontana psychotrifolia H.B.K., this base is
laevorotatory having [α]>D - 243° and gives an ultraviolet spectrum with
absorption maxima at 222, 2S0 and 296 mp. with a shoulder at 272 mil. The
alkaloid may be purified by recrystallization from Me2CO followed by sublima_x0002_tion. It yields a crystalline methiodide, m.p. 272-4°C (dec.) which has an
ultraviolet spectrum containing an absorption maximum at 222 mp. and a
shoulder at 276 mp.. On catalytic hydrogenation with Pt02 as catalyst it gives
the dihydro derivative, m.p. 191-3°C, furnishing a methiodide, m.p. 265-SoC
(dec.). Zn dust distillation yields 3-ethylpyridine and 3-methyl-5-ethylpyridine. | | References | Benoin, Burnell, Medina., Tetrahedron Lett., 807 (1968)
Burnell, Medina., Can. J. Chem., 49,307 (1971) |
| | (19Z)-Anhydrovobasinediol Preparation Products And Raw materials |
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