TRIPHENYLVINYLSILANE

TRIPHENYLVINYLSILANE Basic information
Product Name:TRIPHENYLVINYLSILANE
Synonyms:ethenyltriphenyl-silan;Silane,ethenyltriphenyl-;Triphenylvinylsilan;Triphenyl-vinylsilan;VINYLTRIPHENYLSILANE;TRIPHENYLVINYLSILANE;(triphenylsilyl)ethylene;(Triphenylsilyl)ethylene, Ethenyltriphenylsilane, Vinyltriphenylsilane
CAS:18666-68-7
MF:C20H18Si
MW:286.44
EINECS:242-487-4
Product Categories:Si-(C)4 Compounds;Vinylsilanes, Allylsilanes;Si (Classes of Silicon Compounds)
Mol File:18666-68-7.mol
TRIPHENYLVINYLSILANE Structure
TRIPHENYLVINYLSILANE Chemical Properties
Melting point 68-70 °C(lit.)
Boiling point 190 °C / 3mmHg
density 1.04±0.1 g/cm3(Predicted)
Fp >110°C
storage temp. 2-8°C
form solid
color White to Almost white
Water Solubility Insoluble in water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
BRN 913423
CAS DataBase Reference18666-68-7(CAS DataBase Reference)
EPA Substance Registry SystemSilane, ethenyltriphenyl- (18666-68-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA Yes
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIPHENYLVINYLSILANE Usage And Synthesis
Chemical Propertiesoff-white to slightly beige crystalline powder
UsesTriphenylvinylsilane can be used to produce triphenyl-[2-(tetrahydro-furan-2-yl)-ethyl]-silane at temperature of 190°C. This reaction will need reagent di(t-butyl)peroxide with reaction time of 2 hours. Also employed as an organic light emitting diode.
Purification MethodsIt has been recrystallised from EtOH, 95% EtOH, EtOH/*C6H6, pet ether (b 30-60o) and Et2O, and has been distilled under reduced pressure. [Cason & Brooks J Am Chem Soc 74 4582 1952, Nagel & Post J Org Chem 17 1379 1952, Beilstein 16 IV 1371.]
TRIPHENYLVINYLSILANE Preparation Products And Raw materials
Vinyltrimethoxysilane VINYLTRIPHENYLPHOSPHONIUM BROMIDE Tri(isopropoxy)vinylsilane PHENYLTRIMETHYLSILANE METHYLTRIPHENYLSILANE 1,2,2-Trifluorovinyl-triphenylsilane METHYLPHENYLVINYLSILANE Triphenylsilane Vinyltrimethylsilane Diphenylsilane DIMETHYLDIPHENYLSILANE TRIPHENYLVINYLSILANE Dimethylvinylsilane VINYLPHENYLDIMETHYLSILANE

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