4-Ethylpyridine

4-Ethylpyridine Basic information
Product Name:4-Ethylpyridine
Synonyms:4-ethvlpvridine;4-ethyl-pyridin;Pyridine, 4-ethyl-;GAMMA-ETHYLPYRIDINE;ETHYLPYRIDINE;g-Ethylpyridine;4-Ethylpyridine,98%;4-ETHANOLPYRIDINE
CAS:536-75-4
MF:C7H9N
MW:107.15
EINECS:208-646-7
Product Categories:C7 and C8;Heterocyclic Building Blocks;Pyridines
Mol File:536-75-4.mol
4-Ethylpyridine Structure
4-Ethylpyridine Chemical Properties
Melting point -91 °C
Boiling point 168 °C (lit.)
density 0.942 g/mL at 25 °C (lit.)
refractive index n20/D 1.501(lit.)
Fp 118 °F
storage temp. Flammables area
solubility 107g/l
form Liquid
pkapK1:5.87(+1) (25°C)
color Clear colorless to yellow
PH10 (100g/l, H2O, 20℃)
Water Solubility 34 g/L
Merck 14,3849
BRN 106481
LogP1.650
CAS DataBase Reference536-75-4(CAS DataBase Reference)
NIST Chemistry Reference4-(C2H5)-pyridine(536-75-4)
EPA Substance Registry System4-Ethylpyridine (536-75-4)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 10-36/37/38-20/21/22
Safety Statements 26-36-36/37/39-16
RIDADR UN 2924 3/PG 3
WGK Germany 3
8
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29333999
MSDS Information
ProviderLanguage
4-Ethylpyridine English
SigmaAldrich English
ACROS English
ALFA English
4-Ethylpyridine Usage And Synthesis
Chemical Propertiesclear colorless to yellowish liquid
Uses4-Ethyl pyridine is used as a monomer in polymer chemistry.
Uses4-Ethylpyridine is used to study the influence of counter-anion concentration on analyte retention.
Synthesis Reference(s)The Journal of Organic Chemistry, 22, p. 694, 1957 DOI: 10.1021/jo01357a607
Tetrahedron Letters, 26, p. 275, 1985 DOI: 10.1016/S0040-4039(01)80795-4
General Description4-Ethylpyridine undergoes metal-ligand interaction with Zn-porphyrin which can be studied by mass spectrometry.
Contact allergens4-Ethyl-pyridine is used as a monomer in polymer chemistry
Purification MethodsDry 4-ethylpyridine with BaO, and fractionally distil it. Also purified by converting to the picrate, recrystalising and the free base is regenerated and distilled. [Beilstein 20/6 V 10.]
4-Ethylpyridine Preparation Products And Raw materials
Raw materialsZINC
Preparation Products2-Amino-4-ethylpyridine-->1-PYRIDIN-4-YL-ETHYLAMINE-->2-Ethylpyridine-->4,4'-Bis(methoxycarbonly)-2,2'-bipyridine-->4-Ethyl-2-pyridinecarbonitrile
4-Pyridylacetonitrile hydrochloride 4-Acetylpyridine 4-Pyridineethanesulfonic acid 4-(4-Nitrobenzyl)pyridine Diphenyl(4-pyridyl)methanol 4-Benzoylpyridine 4-Benzylpyridine Ethyl cellulose Hydroxyethyl Cellulose 5-Ethylpyridine,3-ETHYLPYRIDINE,3-ETHYLPYRIDINE 98+% Chromium picolinate BENZ[G]ISOQUINOLINE-5,10-DIONE Ethyl maltol 4-(4-CHLOROBENZOYL)PYRIDINE 4-Ethylpyridine 4-TERT-BUTYLPYRIDINE 4-DIPHENYLMETHYLPYRIDINE 2-ETHYLPYRIDINE 98+%,2-Ethylpyridine,~99%,ALPHA-ETHYLPYRIDINE

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