(S)-(+)-2-Aminobutane

(S)-(+)-2-Aminobutane Basic information
Product Name:(S)-(+)-2-Aminobutane
Synonyms:RARECHEM AK HZ 0019;Butylamine, (S)-sec-;(R)-2-Butylamine,(S)-2-Butylamine;(2S)-2-Butanamine;(2S)-Butane-2-amine;[S,(+)]-2-Butanamine;d-sec-Butylamine;(S)-(+)-2-Aminobutene, 98%
CAS:513-49-5
MF:C4H11N
MW:73.14
EINECS:208-164-7
Product Categories:chiral;Amines (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry
Mol File:513-49-5.mol
(S)-(+)-2-Aminobutane Structure
(S)-(+)-2-Aminobutane Chemical Properties
Melting point -104 °C
Boiling point 63 °C(lit.)
alpha 7.5 º (C=NEAT 19 ºC)
density 0.731 g/mL at 25 °C(lit.)
refractive index n20/D 1.393(lit.)
Fp −3 °F
storage temp. Flammables area
pka10.74±0.10(Predicted)
form liquid
color Clear, colourless
Odorfishy ammonia
optical activity[α]19/D +7.5°, neat
Water Solubility Fully miscible in water.
Sensitive Air Sensitive
Merck 14,1544
BRN 1718760
CAS DataBase Reference513-49-5(CAS DataBase Reference)
NIST Chemistry Reference2-Butanamine, (S)-(513-49-5)
EPA Substance Registry System(S)-2-Aminobutane (513-49-5)
Safety Information
Hazard Codes F,C,N,F+
Risk Statements 11-34-50-35-20/22
Safety Statements 9-16-26-28-36/37/39-45-61-28A
RIDADR UN 2733 3/PG 2
WGK Germany 3
RTECS EO3327000
10-23
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29211999
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
(S)-(+)-2-Aminobutane Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
Chemical PropertiesButyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:
UsesIt is an active pharmaceutical intermediate.
Potential ExposureAlert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs
ShippingUN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material
IncompatibilitiesMay form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics
Waste DisposalUse a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.
(S)-(+)-2-Aminobutane Preparation Products And Raw materials
Raw materials(R)-(-)-2-Aminobutane-->SEC-BUTYLAMINE-->Ethyl acetate-->Isopropenyl acetate-->Methyl 3-methoxypropionate-->2-Butanone oxime-->Vinyl acetate
1-Chloro-2-methylpropane ISOBUTANE 4,4'-Diaminodicyclohexyl methane Cyclooctylamine D-Methionine n-Butane TRANS-2-AMINOCYCLOHEXANOL HYDROCHLORIDE sec-Butylamine N-ACETYL-D-PHENYLALANINE Cycloleucine Cyclohexylamine (S)-(+)-2-Aminobutane 3-CARBAMOYL-PROXYL 1,8-DIAMINO-P-MENTHANE 2-Bromo-2-methylpropane N-Cyclohexyl-2-pyrrolidone 4-Methylcyclohexyl amine N-cyclodecylmethylamine

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